Chromium, pentacarbonyl(trimethylamine)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub80.2 ± 0.7kJ/molN/ABoxhoorn, Ernsting, et al., 1980MS

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
80.2 ± 0.7271.MEBoxhoorn, Ernsting, et al., 1980, 2Based on data from 248. to 293. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.45PEHigginson, Lloyd, et al., 1974Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boxhoorn, Ernsting, et al., 1980
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Thermochim. Acta, 1980, 42, 315. [all data]

Boxhoorn, Ernsting, et al., 1980, 2
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Vapour pressure measurements on M(CO)5L complexes (M «58875» Cr, W; L «58875» CO, P(OØ)3, PØ3, PMe3, NMe3 and pyridazine), Thermochimica Acta, 1980, 42, 3, 315-321, https://doi.org/10.1016/0040-6031(80)85092-1 . [all data]

Higginson, Lloyd, et al., 1974
Higginson, B.R.; Lloyd, D.R.; Connor, J.A.; Hillier, I.H., Photoelectron studies of metal carbonyls. Part 4. Mono-substituted complexes of chromium tungsten carbonyls, J. Chem Soc., J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1418. [all data]


Notes

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