Manganese, tetrafluoro-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + Manganese, tetrafluoro- = (Fluorine anion • Manganese, tetrafluoro-)

By formula: F- + F4Mn = (F- • F4Mn)

Quantity Value Units Method Reference Comment
Δr350. ± 84.kJ/molTDEqKorobov, Chilingarov, et al., 1984gas phase; Fluoride Affinity: 17.5 kcal < MnF3; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
13.5 ± 0.2EIEhlert and Hsia, 1973

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F3Mn+15.5 ± 0.2?EIEhlert and Hsia, 1973 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + Manganese, tetrafluoro- = (Fluorine anion • Manganese, tetrafluoro-)

By formula: F- + F4Mn = (F- • F4Mn)

Quantity Value Units Method Reference Comment
Δr350. ± 84.kJ/molTDEqKorobov, Chilingarov, et al., 1984gas phase; Fluoride Affinity: 17.5 kcal < MnF3; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Korobov, Chilingarov, et al., 1984
Korobov, M.V.; Chilingarov, N.S.; Igolkina, N.A.; Nikitin, M.I.; Sidorov, L.N., Molecules with a high electron affinity. Negative ions in the saturated vapor of the platinum-manganese trifluoride system, Russ. J. Phys. Chem., 1984, 58, 1368. [all data]

Ehlert and Hsia, 1973
Ehlert, T.C.; Hsia, M., Mass spectrometric and thermochemical studies of the manganese fluorides, J. Fluorine Chem., 1973, 2, 33. [all data]


Notes

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