Manganese, tetrafluoro-
- Formula: F4Mn
- Molecular weight: 130.931658
- IUPAC Standard InChI: InChI=1S/4FH.Mn/h4*1H;/q;;;;+4/p-4
- IUPAC Standard InChIKey: KWKYNMDHPVYLQQ-UHFFFAOYSA-J
- CAS Registry Number: 15195-58-1
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
+
= (
•
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By formula: F- + F4Mn = (F- • F4Mn)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 350. ± 84. | kJ/mol | TDEq | Korobov, Chilingarov, et al., 1984 | gas phase; Fluoride Affinity: 17.5 kcal < MnF3; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 13.5 ± 0.2 | EI | Ehlert and Hsia, 1973 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| F3Mn+ | 15.5 ± 0.2 | ? | EI | Ehlert and Hsia, 1973 |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Korobov, Chilingarov, et al., 1984
Korobov, M.V.; Chilingarov, N.S.; Igolkina, N.A.; Nikitin, M.I.; Sidorov, L.N.,
Molecules with a high electron affinity. Negative ions in the saturated vapor of the platinum-manganese trifluoride system,
Russ. J. Phys. Chem., 1984, 58, 1368. [all data]
Ehlert and Hsia, 1973
Ehlert, T.C.; Hsia, M.,
Mass spectrometric and thermochemical studies of the manganese fluorides,
J. Fluorine Chem., 1973, 2, 33. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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