Chlorite

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 17310 ± 20 gas Gilles, Polak, et al., 1992
Distelrath and Boesl, 2000
Wang and Wang, 2000

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 774 ± 25 gas PE Gilles, Polak, et al., 1992
1 Sym. stretch 790 Cs Ar IR Tevault, Chi, et al., 1974
2 Bend 418 Cs Ar IR Tevault, Chi, et al., 1974
b2 3 Asym. stretch 823 Cs Ar IR Tevault, Chi, et al., 1974

Additional references: Jacox, 1994, page 115; Jacox, 2003, page 152

Notes

dPhotodissociation threshold
CsInteraction with cesium

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-, J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352 . [all data]

Distelrath and Boesl, 2000
Distelrath, V.; Boesl, U., Faraday Discuss. Chem. Soc., 2000, 115, 161. [all data]

Wang and Wang, 2000
Wang, W.-B.; Wang, L.-S., The electronic structure and electron affinities of higher chlorine oxide radicals ClO[sub x] (x=2--4) from photoelectron spectroscopy of ClO[sub x][sup -] anions, J. Chem. Phys., 2000, 113, 24, 10928, https://doi.org/10.1063/1.1326067 . [all data]

Tevault, Chi, et al., 1974
Tevault, D.E.; Chi, F.K.; Andrews, L., Infrared spectrum and vibrational potential function of the chlorite anion in the matrix-isolated M+ClO2- species, J. Mol. Spectrosc., 1974, 51, 3, 450, https://doi.org/10.1016/0022-2852(74)90200-8 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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