dichloroethylphosphine
- Formula: C2H5Cl2P
- Molecular weight: 130.941
- CAS Registry Number: 1498-40-4
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 36.8 | 328. | A | Stephenson and Malanowski, 1987 | Based on data from 313. to 385. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.3 | PE | Zverev, Bazhanova, et al., 1983 | LBLHLM |
| 9.70 | PE | Zverev, Bazhanova, et al., 1983 | Vertical value; LBLHLM |
| 9.70 ± 0.05 | PE | Westwood, Kroto, et al., 1979 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Zverev, Bazhanova, et al., 1983
Zverev, V.V.; Bazhanova, Z.G.; Villem, N.V.; Villem, Ya.Ya.,
Photoelectron spectra and electronic structure of organophosphorous compounds of tricoordinated phosphorus with a phosphorus-sulfur bond,
J. Gen. Chem. USSR, 1983, 53, 1775, In original 1968. [all data]
Westwood, Kroto, et al., 1979
Westwood, N.P.C.; Kroto, H.W.; Nixon, J.F.; Simmons, N.P.C.,
Formation of 1-phosphapropyne, CH3C≡P, by pyrolysis of dichloro(ethyl)phosphine: a He(I) photoelectron spectroscopic study,
J. Chem. Soc. Dalton Trans., 1979, 9, 1405. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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