Chromyl chloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
254.8 to 390.33.941831256.761-70.862Stull, 1947Coefficents calculated by NIST from author's data.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.6PELee and Rabalais, 1975LLK
11.99 ± 0.04EIFlesch, White, et al., 1969RDSH
11.8PELee and Rabalais, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CrCl+16.52 ± 0.07?EIFlesch, White, et al., 1969RDSH
CrOCl+14.80 ± 0.05?EIFlesch, White, et al., 1969RDSH
CrO2Cl+13.69 ± 0.06ClEIFlesch, White, et al., 1969RDSH
CrCl2+14.00 ± 0.10O2EIFlesch, White, et al., 1969RDSH
CrOCl2+15.52 ± 0.11OEIFlesch, White, et al., 1969RDSH
Cr+19.15 ± 0.07?EIFlesch, White, et al., 1969RDSH
CrO+18.30 ± 0.10?EIFlesch, White, et al., 1969RDSH
CrO2+14.18 ± 0.08?EIFlesch, White, et al., 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Lee and Rabalais, 1975
Lee, T.H.; Rabalais, J.W., Photoelectron spectrum ground state electronic structure of chromyl chloride vapor, Chem. Phys. Lett., 1975, 34, 135. [all data]

Flesch, White, et al., 1969
Flesch, G.D.; White, R.M.; Svec, H.J., The positive and negative ion mass spectra of chromyl chloride and chromyl fluoride, Intern. J. Mass Spectrom. Ion Phys., 1969, 3, 339. [all data]


Notes

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