Manganese, pentacarbonyliodo-
- Formula: C5IMnO5
- Molecular weight: 321.8930
- IUPAC Standard InChIKey: IGYXZZLAUYRNTO-UHFFFAOYSA-M
- CAS Registry Number: 14879-42-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Manganese pentacarbonyl iodide; Manganese, pentacarbonyliodo-, (OC-6-22)-; Iodine manganese pentacarbonyl; Iodomanganese pentacarbonyl; Pentacarbonyliodomanganese; Mn(CO)5I
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.55 ± 0.02 | EI | Junk, Svec, et al., 1968 | RDSH |
8.40 ± 0.05 | PE | Higginson, Lloyd, et al., 1975 | Vertical value; LLK |
8.44 | PE | Lichtenberger, Sarapu, et al., 1973 | Vertical value; LLK |
8.35 | PE | Evans, Green, et al., 1969 | Vertical value; RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
COIMn+ | 12.37 | 4CO | EI | Junk, Svec, et al., 1968 | RDSH |
MnCO+ | 14.4 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
C2O2IMn+ | 10.46 | 3CO | EI | Junk, Svec, et al., 1968 | RDSH |
C3O3IMn+ | 9.49 | 2CO | EI | Junk, Svec, et al., 1968 | RDSH |
MnC3O3+ | 12.13 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
MnI+ | 14.0 | 5CO | EI | Junk, Svec, et al., 1968 | RDSH |
Mn+ | 16.2 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J.,
Electron impact studies of manganese and rhenium pentacarbonyl halides,
J. Am. Chem. Soc., 1968, 90, 5758. [all data]
Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F.,
Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]
Lichtenberger, Sarapu, et al., 1973
Lichtenberger, D.L.; Sarapu, A.C.; Fenske, R.F.,
Photoelectron spectra and electronic structure of pentacarbonylmanganese halides,
Inorg. Chem., 1973, 12, 702. [all data]
Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W.,
Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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