Iron, hexacarbonylbis[μ-(methanethiolato)]di-, (Fe-Fe)

• Formula: C₈H₆Fe₂O₆S₂
• Molecular weight: 373.950
• IUPAC Standard InChI: InChI=1S/6CO.2CH3S.2Fe/c8*1-2;;/h;;;;;;2*1H3;; Copy

  
• IUPAC Standard InChIKey: DWAKKZOFWUECIF-UHFFFAOYSA-N Copy
• CAS Registry Number: 14878-96-7
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Bis(μ-methylmercapto)bis(tricarbonyliron); Iron, hexacarbonylbis[μ-(methanethiolato)]di-,; Di-μ-methanethiolato-hexacarbonyl-diiron; hexacarbonylbis[μ-(methanethiolato)]diiron
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Connor and Göbel, 1995
Connor, Joseph A.; Göbel, Andreas, Thermochemistry of sulfide and thiolato derivatives of iron carbonyl, and the strengths of the iron---sulfur bonds, The Journal of Chemical Thermodynamics, 1995, 27, 6, 605-611, https://doi.org/10.1006/jcht.1995.0062 . [all data]

Junk, Preston, et al., 1970
Junk, G.A.; Preston, F.J.; Svec, H.J.; Thompson, D.T., Ligand effects on the ionization potentials and bond energies of some L¹L²Fe₂(CO)₆ complexes, J. Chem. Soc. A, 1970, 3171. [all data]

Notes

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• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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