Dibromosilylene
- Formula: Br2Si
- Molecular weight: 187.893
- IUPAC Standard InChIKey: KBDJQNUZLNUGDS-UHFFFAOYSA-N
- CAS Registry Number: 14877-32-8
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
View reactions leading to Br2Si+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
>1.7 | EIAE | Pabst, Margrave, et al., 1977 | From SiBr4; G2MP2 calculations indicate an EA of ca. 1.3 eV; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
~8.5 | DER | Creasey, Lambert, et al., 1991 | LL |
12. ± 1. | EI | Farber and Srivastava, 1980 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pabst, Margrave, et al., 1977
Pabst, R.E.; Margrave, J.L.; Franklin, J.L.,
Electron impact studies of the tetrachlorides and tetrabromides of silicon and germanium,
Int. J. Mass Spectrom. Ion Phys., 1977, 25, 361. [all data]
Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Leszek, J.F.; Hatherly, P.A.; Stankiewicz, M.,
Photoionization mass-spectrometric study of fragmentation of SiBr4 and GeBr4 in the range 400-1220 A,
J. Chem. Soc. Faraday Trans., 1991, 87, 3717. [all data]
Farber and Srivastava, 1980
Farber, M.; Srivastava, R.D.,
Mass spectrometric determination of the heats of formation of the silicon bromides SiBr(g), SiBr2(g), and SiBr3(g).,
High Temp. Sci., 1980, 12, 21. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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