Cupric trifluoroacetylacetonate

• Formula: C₁₀H₂CuF₁₂O₄
• Molecular weight: 477.647
• IUPAC Standard InChI: InChI=1S/2C5HF6O2.Cu/c2*6-4(7,8)2(12)1-3(13)5(9,10)11;/h2*1H;/q2*-2;+4 Copy

  
• IUPAC Standard InChIKey: YNWOLWXNDUSOKR-UHFFFAOYSA-N Copy
• CAS Registry Number: 14781-45-4
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Copper(II) hexafluoroacetylacetonate; Copper, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O')-, (SP-4-1)-; bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')copper; Copper bis(trifluoroacetylacetonate)
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva and Ferrão, 1988
Ribeiro da Silva, Manuel A.V.; Ferrão, Maria Luisa C.C.H., Standard enthalpies of formation of bis(trifluoroacetylacetonato)copper(II) and bis(hexafluoroacetylacetonato)copper(II): the mean (Cu«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1988, 20, 3, 359-361, https://doi.org/10.1016/0021-9614(88)90132-2 . [all data]

Reichert, Bancroft, et al., 1970
Reichert, C.; Bancroft, G.M.; Westmore, J.B., Mass spectral studies of metal chelates. V. Mass spectra and appearance potentials of some fluorine-substituted acetylacetonates, Can. J. Chem., 1970, 48, 1362. [all data]

Holtzclaw, Lintvedt, et al., 1969
Holtzclaw, H.F., Jr.; Lintvedt, R.L.; Baumgarten, H.E.; Parker, R.G.; Bursey, M.M.; Rogerson, P.F., Mass spectra of metal chelates. I. Substituent effects on ionization potentials and fragmentation patterns of some 1-methyl-3-alkyl-1,3-dione-copper(II) chelates, J. Am. Chem. Soc., 1969, 91, 3774. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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