Cupric trifluoroacetylacetonate


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub108. ± 6.kJ/molCRibeiro da Silva and Ferrão, 1988 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.86 ± 0.05EIReichert, Bancroft, et al., 1970RDSH
9.68 ± 0.01EIHoltzclaw, Lintvedt, et al., 1969RDSH
10.20PECauletti, Furlani, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C9H2O4F9Cu+11.6 ± 0.1?EIReichert, Bancroft, et al., 1970RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin MUS21 A. Mujsce, AT&T Bell Labs., Murray Hill, N.J., USA
NIST MS number 115417

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva and Ferrão, 1988
Ribeiro da Silva, Manuel A.V.; Ferrão, Maria Luisa C.C.H., Standard enthalpies of formation of bis(trifluoroacetylacetonato)copper(II) and bis(hexafluoroacetylacetonato)copper(II): the mean (Cu«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1988, 20, 3, 359-361, https://doi.org/10.1016/0021-9614(88)90132-2 . [all data]

Reichert, Bancroft, et al., 1970
Reichert, C.; Bancroft, G.M.; Westmore, J.B., Mass spectral studies of metal chelates. V. Mass spectra and appearance potentials of some fluorine-substituted acetylacetonates, Can. J. Chem., 1970, 48, 1362. [all data]

Holtzclaw, Lintvedt, et al., 1969
Holtzclaw, H.F., Jr.; Lintvedt, R.L.; Baumgarten, H.E.; Parker, R.G.; Bursey, M.M.; Rogerson, P.F., Mass spectra of metal chelates. I. Substituent effects on ionization potentials and fragmentation patterns of some 1-methyl-3-alkyl-1,3-dione-copper(II) chelates, J. Am. Chem. Soc., 1969, 91, 3774. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]


Notes

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