Rhenium, pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub21. ± 1.kcal/molN/AAddison, Connor, et al., 1998 

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
13.5451.Baev, Dem'yanchuk, et al., 1971Based on data from 440. to 463. K.
13.5451.Baev, Dem'yanchuk, et al., 1971Based on data from 440. to 463. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
26.1 ± 1.363.CAddison, Connor, et al., 1998 
16.4401.MMBaev, Dem'yanchuk, et al., 1971Based on data from 363. to 440. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.22 ± 0.01EIMichels and Svec, 1981LLK
8.14 ± 0.01EIJunk and Svec, 1970RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CMnO+19.05?EISvec and Junk, 1967RDSH
CMnORe+23.009COEISvec and Junk, 1967RDSH
C2MnO2Re+19.758COEISvec and Junk, 1967RDSH
C3MnO3Re+16.947COEISvec and Junk, 1967RDSH
C4MnO4Re+14.656COEISvec and Junk, 1967RDSH
C5MnO5+10.50?EIJunk and Svec, 1970RDSH
C5MnO5Re+12.125COEISvec and Junk, 1967RDSH
C5O5Re+10.80?EISvec and Junk, 1967RDSH
C6O6Re+9.36?EISvec and Junk, 1967RDSH
Mn+25.67?EISvec and Junk, 1967RDSH
MnRe+25.9810COEISvec and Junk, 1967RDSH
Re+30.93?EISvec and Junk, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Addison, Connor, et al., 1998
Addison, Susan J.; Connor, Joseph A.; Kinkaid, John A., High temperature microcalorimetric studies of the thermal decomposition and halogenation of nonacarbonylcobaltmanganese, nonacarbonylcobaltrhenium and decacarbonylmanganeserhenium, Journal of Organometallic Chemistry, 1998, 554, 2, 123-127, https://doi.org/10.1016/S0022-328X(97)00663-3 . [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]


Notes

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