Stannane, tetrabutyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap82.8 ± 2.1kJ/molCC-SBDavies, Pope, et al., 1963MS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
67.8 ± 0.5425.Baev, 2001Based on data from 389. to 462. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
373.8 to 573.84.957522882.0446.532Umilin and Tsinovoi, 1968Coefficents calculated by NIST from author's data.

Gas phase ion energetics data

Go To: Top, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.76PEKochi, 1980Vertical value; LLK
8.7PESchweig, Weidner, et al., 1973Vertical value; LLK

Gas Chromatography

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L190.1599.Putnam and Pu, 1965Celite; Column length: 1. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
PackedApiezon L1588.Putnam and Pu, 1965, 2Celite, 10. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L1594.Putnam and Pu, 1965, 2Celite, 15. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L1593.Putnam and Pu, 1965, 2Celite, 6. K/min; Column length: 3. m; Tstart: 60. C

References

Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Umilin and Tsinovoi, 1968
Umilin, V.A.; Tsinovoi, Y.N., Vapor Pressure of Tetrabutyltin, Zh. Fiz. Khim., 1968, 42, 2320-2322. [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Schweig, Weidner, et al., 1973
Schweig, A.; Weidner, U.; Manuel, G., Theory and application of photoelectron spectroscopy. XVI. Photoelectron spectroscopy and molecular conformations: Ge-C and Sn-C hyperconjugation and the conformation of allylgermanes and stannanes, J. Organomet. Chem., 1973, 54, 145. [all data]

Putnam and Pu, 1965
Putnam, R.C.; Pu, H., Retention indices of organotins, J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160 . [all data]

Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H., Retention indices of organotins (II), J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289 . [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References