Chlorine nitrate
- Formula: ClNO3
- Molecular weight: 97.458
- IUPAC Standard InChIKey: XYLGPCWDPLOBGP-UHFFFAOYSA-N
- CAS Registry Number: 14545-72-3
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+ = ClN2O6-
By formula: NO3- + ClNO3 = ClN2O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.3 ± 5.7 | kcal/mol | IMRB | Wincel, Mereand, et al., 1997 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.04 | PE | Wang, Li, et al., 1996 | |
11.56 | PE | Wang, Li, et al., 1996 | Vertical value |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
ClO+ | 12.33 | NO2 | PI | Jochims, Denzer, et al., 1992 | |
NO+ | 13.1 | ? | PI | Jochims, Denzer, et al., 1992 | |
NO2+ | 11.07 | ClO | PI | Jochims, Denzer, et al., 1992 | |
NO2+ | 13.7 ± 0.1 | Cl+O | PI | Jochims, Denzer, et al., 1992 |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W.,
Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-,
J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146
. [all data]
Wang, Li, et al., 1996
Wang, D.; Li, Y.; Jiang, P.; Wang, X.; Chen, B.,
The study of HeI photoelectron spectroscopy (PES) of the electronic structure for ClONO2,
Chem. Phys. Lett., 1996, 260, 99. [all data]
Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H.,
Photochemical decay reactions of N2O5, HNO3, ClNO3 and BrNO3 in the energy range 10-20 eV,
Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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