Methyl rhenium pentacarbonyl
- Formula: C6H3O5Re
- Molecular weight: 341.292
- CAS Registry Number: 14524-92-6
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -757.0 ± 8.7 | kJ/mol | Review | Martinho Simões | |
ΔfH°gas | -758.1 ± 6.0 | kJ/mol | Review | Martinho Simões | |
ΔfH°gas | -757.6 ± 5.5 | kJ/mol | Review | Martinho Simões | Selected data. Average of the values from Brown, Connor, et al., 1974 and Al-Takhin, Connor, et al., 1983 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 774.9 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 745.9 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.71 ± 0.05 | PE | Higginson, Lloyd, et al., 1975 | Vertical value; LLK |
8.72 | PE | Hall, 1975 | Vertical value; LLK |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A.,
J. Organometal. Chem., 1974, 81, 403. [all data]
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F.,
Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]
Hall, 1975
Hall, M.B.,
The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls,
J. Am. Chem. Soc., 1975, 97, 2057. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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