Disilane, hexaphenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub50.00 ± 0.50kcal/molME,TECalle and Kana'an, 1974 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
8.16 ± 0.15EIGaidis, Briggs, et al., 1971

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C18H15Si+9.61 ± 0.09(C6H5)3SiEIGaidis, Briggs, et al., 1971 

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin DOW CORNING CORP.
Source reference COBLENTZ NO. 5590
Date 1965/11/05
Name(s) 1,1,1,2,2,2-hexaphenyldisilane
State SOLID (MULL)
Instrument PERKIN-ELMER 521 (GRATING)
SPECTRAL CONTAMINATION DUE TO OIL AROUND 2930, 1455 AND 1372 CM-1
Instrument parameters FILTERS AT 3150, 2500, 2000, 1150, 700, 410. GRATING CHANGES: 2000, 630
Resolution 2
Melting point 369 C

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Calle and Kana'an, 1974
Calle, Luz M.; Kana'an, Adli S., Enthalpies and entropies of sublimation of tetraphenyl silane and hexaphenyl disilane. The bond dissociation energies of Si«58872»C and Si«58872»Si, The Journal of Chemical Thermodynamics, 1974, 6, 10, 935-942, https://doi.org/10.1016/0021-9614(74)90214-6 . [all data]

Gaidis, Briggs, et al., 1971
Gaidis, J.M.; Briggs, P.R.; Shannon, T.W., Mass spectra of disilanes. Phenyl-silicon interaction and silicon-silicon bond strength, J. Phys. Chem., 1971, 75, 974. [all data]


Notes

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