H2PF
- Formula: FH2P
- Molecular weight: 51.98805
- CAS Registry Number: 14500-81-3
- Information on this page:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 1 | PH2 s-stretch | 2283.12 | gas | IR | Beckers, 1993 Beckers, Burger, et al., 1994 Beckers, Burger, et al., 1995 | |
| 1 | PH2 s-stretch | 2304 | Ar | IR | Andrews and Withnall, 1989 | ||
| 2 | PH2 deform. | 1109.24 | gas | IR | Beckers, 1993 Beckers, Burger, et al., 1994 | ||
| 2 | PH2 deform. | 1090 | Ar | IR | Andrews and Withnall, 1989 | ||
| 3 | PH2 deform. | 976.50 | gas | IR | Beckers, Burger, et al., 1994 | ||
| 3 | PH2 deform. | 934 | Ar | IR | Andrews and Withnall, 1989 | ||
| 4 | PF stretch | 807.36 | gas | IR | Beckers, 1993 Beckers, Burger, et al., 1994 | ||
| 4 | PF stretch | 795 | vs | Ar | IR | Andrews and Withnall, 1989 | |
| a | 5 | PH2 a-stretch | 2286.97 | gas | IR | Beckers, 1993 Beckers, Burger, et al., 1994 Beckers, Burger, et al., 1995 | |
| 5 | PH2 a-stretch | 2310 | Ar | IR | Andrews and Withnall, 1989 | ||
Additional references: Jacox, 1994, page 153; Jacox, 1998, page 228; Drean, Paplewski, et al., 1996
Notes
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Beckers, 1993
Beckers, H.,
Gasphasenreaktionen von H3PF2: Darstellung der Monohalogenphosphane H2PF und H2PCl,
Z. Anorg. Allg. Chem., 1993, 619, 11, 1880, https://doi.org/10.1002/zaac.19936191111
. [all data]
Beckers, Burger, et al., 1994
Beckers, H.; Burger, H.; Kuna, R.; Paplewski, M.; Thiel, W.,
Ab initio calculations on monohalogenophosphanes PH2X (X=F,Cl,Br,I), and experimental detection and characterization of PH2F and PH2Cl by high resolution infrared spectroscopy,
J. Chem. Phys., 1994, 101, 7, 5585, https://doi.org/10.1063/1.468460
. [all data]
Beckers, Burger, et al., 1995
Beckers, H.; Burger, H.; Paplewski, M.,
High-Resolution FTIR Study of the PH Stretching Bands ν1 and ν5 of PH2F and PH2Cl,
J. Mol. Spectrosc., 1995, 171, 2, 546, https://doi.org/10.1006/jmsp.1995.1141
. [all data]
Andrews and Withnall, 1989
Andrews, L.; Withnall, R.,
Cocondensation reaction between phosphine and fluorine: matrix infrared spectra of difluorophosphorane, difluorophosphine and fluorophosphine,
Inorg. Chem., 1989, 28, 3, 494, https://doi.org/10.1021/ic00302a023
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Drean, Paplewski, et al., 1996
Drean, P.; Paplewski, M.; Demaison, J.; Breidung, J.; Thiel, W.; Beckers, H.; Burger, H.,
Millimeter-Wave Spectra,,
Inorg. Chem., 1996, 35, 26, 7671, https://doi.org/10.1021/ic960546f
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.