Methyl germane

• Formula: CH₆Ge
• Molecular weight: 90.70
• CAS Registry Number: 1449-65-6
• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH₅Ge^- +  = CH₆Ge

By formula: CH₅Ge^- + H⁺ = CH₆Ge

Gas phase ion energetics data

Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

De-protonation reactions

CH₅Ge^- +  = CH₆Ge

By formula: CH₅Ge^- + H⁺ = CH₆Ge

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Amberger and Boeters, 1961
Amberger, E.; Boeters, H., Darstellung der Methylchlorgermane, Angew. Chem., 1961, 73, 3, 114-114, https://doi.org/10.1002/ange.19610730309 . [all data]

Griffiths and Onyszchuk, 1961
Griffiths, J.E.; Onyszchuk, M., ORGANOGERMANIUM COMPOUNDS: PART I. THE INTERACTION OF HEXAMETHYLDIGERMOXANE AND TRIMETHYLMETHOXYGERMANE WITH BORON TRIFLUORIDE, Can. J. Chem., 1961, 39, 2, 339-347, https://doi.org/10.1139/v61-040 . [all data]

Decouzon, Gal, et al., 1993
Decouzon, M.; Gal, J.F.; Gayraud, J.; Maria, P.C.; Vaglio, G.A.; Volpe, P., Fourier Transform-Ion Cyclotron Resonance Study of the Gas-Phase Acidities of Germane and Methylgermane - Bond Dissociation Energy of German, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 54, https://doi.org/10.1016/1044-0305(93)85042-V . [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Drake, Glavincevski, et al., 1979
Drake, J.E.; Glavincevski, B.M.; Gorzelska, K., The photoelectron spectra of methylgermane, trifluoro- and trichloro-methylgermane, J. Electron Spectrosc. Relat. Phenom., 1979, 17, 73. [all data]

Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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