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Methyl germane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.0PEDrake, Glavincevski, et al., 1979LLK
11.00PEDrake, Glavincevski, et al., 1979Vertical value; LLK

De-protonation reactions

CH5Ge- + Hydrogen cation = CH6Ge

By formula: CH5Ge- + H+ = CH6Ge

Quantity Value Units Method Reference Comment
Deltar1537. ± 8.8kJ/molG+TSDecouzon, Gal, et al., 1993gas phase; B
Deltar1534. ± 8.8kJ/molG+TSGal, Decouzon, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar1503. ± 8.4kJ/molIMREDecouzon, Gal, et al., 1993gas phase; B
Deltar1501. ± 8.4kJ/molIMREGal, Decouzon, et al., 2001gas phase; B

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Drake, Glavincevski, et al., 1979
Drake, J.E.; Glavincevski, B.M.; Gorzelska, K., The photoelectron spectra of methylgermane, trifluoro- and trichloro-methylgermane, J. Electron Spectrosc. Relat. Phenom., 1979, 17, 73. [all data]

Decouzon, Gal, et al., 1993
Decouzon, M.; Gal, J.F.; Gayraud, J.; Maria, P.C.; Vaglio, G.A.; Volpe, P., Fourier Transform-Ion Cyclotron Resonance Study of the Gas-Phase Acidities of Germane and Methylgermane - Bond Dissociation Energy of German, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 54, https://doi.org/10.1016/1044-0305(93)85042-V . [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]


Notes

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