potassium tetrafluoroaluminate


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

AlF4- + AlF4K = (AlF4- • AlF4K)

By formula: AlF4- + AlF4K = (AlF4- • AlF4K)

Quantity Value Units Method Reference Comment
Δr147. ± 6.3kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Δr123. ± 10.kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

F2O2P- + AlF4K = (F2O2P- • AlF4K)

By formula: F2O2P- + AlF4K = (F2O2P- • AlF4K)

Quantity Value Units Method Reference Comment
Δr177. ± 21.kJ/molN/AMavrin, Miletich, et al., 1989gas phase; ΔHf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
13.02 ± 0.05PELassiter, Allen, et al., 1980Vertical value

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

AlF4- + AlF4K = (AlF4- • AlF4K)

By formula: AlF4- + AlF4K = (AlF4- • AlF4K)

Quantity Value Units Method Reference Comment
Δr147. ± 6.3kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Δr123. ± 10.kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

F2O2P- + AlF4K = (F2O2P- • AlF4K)

By formula: F2O2P- + AlF4K = (F2O2P- • AlF4K)

Quantity Value Units Method Reference Comment
Δr177. ± 21.kJ/molN/AMavrin, Miletich, et al., 1989gas phase; ΔHf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Mavrin, Miletich, et al., 1989
Mavrin, A.A.; Miletich, M.; Korobov, M.V.; Zmbov, K.; Sidorov, L.N., Mass-spectroscopic Thermodynamic Study of the Negative Ions of Phosphorous Oxide Fluorides, Russ. J. Phys. Chem., 1989, 63, 500. [all data]

Lassiter, Allen, et al., 1980
Lassiter, T.W.; Allen, J.D., Jr.; Schweitzer, G.K., The photoelectron spectroscopic characterization of vapors above heated alkali tetrafluoroaluminates, alkali tetrachloroaluminates, ammonium tetrachloroaluminate, J. Electron Spectrosc. Relat. Phenom., 1980, 19, 321. [all data]


Notes

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