Diisopropyl methanephosphonate

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Mass spectrum (electron ionization)

Go To: Top, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Diisopropyl methanephosphonate

Mass Spectrum

30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
0
20
40
60
80
100
120
m/z
Relative Intensity

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin VERIFINN
NIST MS number 289532

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySE-541073.Kostiainen, 200025. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min, 280. C @ 10. min

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySE-541066.Budiman, 200730. m/0.25 mm/0.25 μm, Helium, 40. C @ 1. min, 10. K/min, 280. C @ 5. min
CapillarySE-541075.Budiman, 200730. m/0.25 mm/0.25 μm, Helium, 40. C @ 1. min, 10. K/min, 280. C @ 5. min
CapillarySE-541085.Budiman, 200730. m/0.25 mm/0.25 μm, Helium, 40. C @ 1. min, 10. K/min, 280. C @ 5. min
CapillaryDB-51067.Savel'eva, Zenkevich, et al., 200225. m/0.20 mm/0.33 μm, Helium, 40. C @ 1. min, 5. K/min, 270. C @ 15. min
CapillarySE-541072.7Söderström, Ketola, et al., 199525. m/0.32 mm/0.25 μm, He, 40. C @ 2. min, 10. K/min, 250. C @ 10. min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySE-541073.Budiman, 200730. m/0.25 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5 MS1059.Tsunoda, 200530. m/0.25 mm/0.25 μm, Helium; Program: 45 0C (2 min) 8 0C/min -> 125 0C 15 0C/min -> 280 0C
CapillaryDB-5 MS1058.Tsunoda, 200530. m/0.25 mm/0.25 μm, Helium; Program: 45 0C (2 min) 8 0C/min -> 125 0C 15 0C/min -> 280 0C
CapillaryDB-51067.Saveljeva, Zenkevich, et al., 2003He; Program: not specified
Capillary5 % Phenyl methyl siloxane1073.OPCW, 1997Program: not specified

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kostiainen, 2000
Kostiainen, O., Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]

Budiman, 2007
Budiman, H., Analysis and identification spiking chemical compounds related to chemical weapon convention in unknown water samples using gas chromatography and gas chromatography electron ionization mass spectrometry, Indo. J. Chem., 2007, 7, 3, 297-302. [all data]

Savel'eva, Zenkevich, et al., 2002
Savel'eva, E.I.; Zenkevich, I.G.; Kuznetsova, T.A.; Radilov, A.S.; Pshenichnaya, G.V., Investigation of Products of Transformation of Phosphororganic Toxic Substances with Gas Chromatography - Mass Spectrometry, Rus. Khim. Zh. (Rus.), 2002, 56, 6, 82-91. [all data]

Söderström, Ketola, et al., 1995
Söderström, M.T.; Ketola, R.A.; Kostiainen, O., Identification of some nerve agent homologues and dialkyl methylphosphonates by gas chromatography/Fourier transform infrared spectrometry. Part II. Spectral search with the help of retention indices, Fresenius J. Anal. Chem., 1995, 352, 6, 550-556, https://doi.org/10.1007/BF00323072 . [all data]

Tsunoda, 2005
Tsunoda, N., The sarin incidents in Japan and mass spectrometry, J. MAss Spectrom. Soc. Japan, 2005, 53, 3, 157-163, https://doi.org/10.5702/massspec.53.157 . [all data]

Saveljeva, Zenkevich, et al., 2003
Saveljeva, E.; Zenkevich, I.; Radilov, A., Identification of chemical neutralization and products of organophosphorus chemical warfare agents, 2003, retrieved from http://www.shimadzu.com/apps/form.cfm. [all data]

OPCW, 1997
OPCW, Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/cseries/csp1/CIDEC64.html. [all data]


Notes

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References