4,N,N',N''-Tetramethyl-2,6,7-triaza-1-phosphabicyclo[2.2.2]octane
- Formula: C8H18N3P
- Molecular weight: 187.2224
- IUPAC Standard InChI: InChI=1S/C8H18N3P/c1-8-5-9(2)12(10(3)6-8)11(4)7-8/h5-7H2,1-4H3
- IUPAC Standard InChIKey: VHSLEILOALHGTF-UHFFFAOYSA-N
- CAS Registry Number: 14418-26-9
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C8H18N3P+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 6.8 | PE | Cowley, Goodman, et al., 1977 | LLK |
| 7.71 ± 0.10 | PE | Cowley, Lattman, et al., 1982 | Vertical value; LBLHLM |
| 8.3 | PE | Arshinova, Zverev, et al., 1981 | Vertical value; LLK |
| 7.71 | PE | Cowley, Goodman, et al., 1977 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cowley, Goodman, et al., 1977
Cowley, A.H.; Goodman, D.W.; Kuebler, N.A.; Sanchez, M.; Verkade, J.G.,
Molecular photoelectron spectroscopic investigation of some caged phosphorus compounds and related acyclic species,
Inorg. Chem., 1977, 16, 854. [all data]
Cowley, Lattman, et al., 1982
Cowley, A.H.; Lattman, M.; Stricklen, P.M.; Verkade, J.G.,
UV photoelectron spectroscopic investigation of some polycyclic group 5A compounds and related acyclic species. 1. Free and coordinated aminophosphines and related compounds,
Inorg. Chem., 1982, 21, 543. [all data]
Arshinova, Zverev, et al., 1981
Arshinova, R.P.; Zverev, V.V.; Villem, Y.Y.; Villem, N.V.,
Ionization potentials, electron structures, and steric structures of tervalent-phosphorus di-and tri-esters,
J. Gen. Chem. USSR, 1981, 51, 1503, In original 1757. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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