Copper octaethylporphyrin
- Formula: C36H44CuN4
- Molecular weight: 596.307
- IUPAC Standard InChI: InChI=1S/C36H44N4.Cu/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
- IUPAC Standard InChIKey: WYWUPEFEFRBNGN-XTPDIVBZSA-N
- CAS Registry Number: 14409-63-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Octaethyl-porphyrin, Cu-derivative; Aetio-porphyrin, Cu-derivative; Cu-OEP complex; 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine copper
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Options:
Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 6.31 ± 0.03 | PE | Kitagawa, Morishima, et al., 1979 | Vertical value |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 5390. | Marriott, Gill, et al., 1982 | H2, 7. K/min; Column length: 6. m; Column diameter: 0.30 mm; Tstart: 60. C; Tend: 300. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | CP Sil 5 CB | 5390. | Marriott, Gill, et al., 1982, 2 | H2; Column length: 20. m; Column diameter: 0.34 mm; Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kitagawa, Morishima, et al., 1979
Kitagawa, S.; Morishima, I.; Yonezawa, T.; Sato, N.,
Photoelectron spectroscopic study on metallooctaethylporphyrins,
Inorg. Chem., 1979, 18, 1345. [all data]
Marriott, Gill, et al., 1982
Marriott, P.J.; Gill, J.P.; Eglinton, G.,
Capillary Gas Chromatography of Metal-Porphyrin Complexes,
J. Chromatogr., 1982, 236, 2, 395-401, https://doi.org/10.1016/S0021-9673(00)84890-6
. [all data]
Marriott, Gill, et al., 1982, 2
Marriott, P.J.; Gill, J.P.; Evershed, R.P.; Eglinton, G.; Maxwell, J.R.,
Capillary GC and GC-MS of porphyrins and metalloporphyrins,
Chromatographia, 1982, 16, 1, 304-308, https://doi.org/10.1007/BF02258926
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.