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bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.1 ± 0.1EIReichert, Bancroft, et al., 1970RDSH
8.61 ± 0.05EIHoltzclaw, Lintvedt, et al., 1969RDSH
8.95PECauletti, Furlani, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H4O2F3Cu+13.1 ± 0.1?EIReichert, Bancroft, et al., 1970RDSH
C9H8O4F3Cu+11.5 ± 0.1?EIReichert, Bancroft, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reichert, Bancroft, et al., 1970
Reichert, C.; Bancroft, G.M.; Westmore, J.B., Mass spectral studies of metal chelates. V. Mass spectra and appearance potentials of some fluorine-substituted acetylacetonates, Can. J. Chem., 1970, 48, 1362. [all data]

Holtzclaw, Lintvedt, et al., 1969
Holtzclaw, H.F., Jr.; Lintvedt, R.L.; Baumgarten, H.E.; Parker, R.G.; Bursey, M.M.; Rogerson, P.F., Mass spectra of metal chelates. I. Substituent effects on ionization potentials and fragmentation patterns of some 1-methyl-3-alkyl-1,3-dione-copper(II) chelates, J. Am. Chem. Soc., 1969, 91, 3774. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]


Notes

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