Dirhenium decacarbonyl


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.49 ± 0.02EIMichels and Svec, 1981LLK
8.36 ± 0.03EIJunk and Svec, 1970RDSH
8.07PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.86PEHall, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CORe2+26.269COEISvec and Junk, 1967RDSH
C2O2Re2+23.558COEISvec and Junk, 1967RDSH
C3O3Re2+21.467COEISvec and Junk, 1967RDSH
C4O4Re+13.30?EISvec and Junk, 1967RDSH
C4O4Re2+19.316COEISvec and Junk, 1967RDSH
C5O5Re+10.34?EIJunk and Svec, 1970RDSH
C5O5Re2+16.715COEISvec and Junk, 1967RDSH
C6O6Re2+15.014COEISvec and Junk, 1967RDSH
C7O7Re2+13.553COEISvec and Junk, 1967RDSH
C8O8Re2+10.892COEISvec and Junk, 1967RDSH
C9O9Re2+9.57COEISvec and Junk, 1967RDSH
Re+37.55?EISvec and Junk, 1967RDSH
Re2+28.9610COEISvec and Junk, 1967RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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Origin Chemical Concepts
NIST MS number 154911

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Hall, 1975
Hall, M.B., The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls, J. Am. Chem. Soc., 1975, 97, 2057. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References