bromopentacarbonylrhenium
- Formula: C5BrO5Re
- Molecular weight: 406.161
- CAS Registry Number: 14220-21-4
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -204.9 ± 1.8 | kcal/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -226.9 ± 1.7 | kcal/mol | Review | Martinho Simões |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 22.0 ± 0.5 | kcal/mol | HAL-HFC | Al-Takhin, Connor, et al., 1983 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.07 ± 0.02 | EI | Junk, Svec, et al., 1968 | RDSH |
8.83 | PE | Higginson, Lloyd, et al., 1975 | Vertical value; LLK |
8.80 | PE | Hall, 1975 | Vertical value; LLK |
8.86 | PE | Ceasar, Milazzo, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
ReBr+ | 19.51 | 5CO | EI | Junk, Svec, et al., 1968 | RDSH |
COBrRe+ | 16.94 | 4CO | EI | Junk, Svec, et al., 1968 | RDSH |
C2O2BrRe+ | 15.02 | 3CO | EI | Junk, Svec, et al., 1968 | RDSH |
C3O3BrRe+ | 11.97 | 2CO | EI | Junk, Svec, et al., 1968 | RDSH |
C3O3Re+ | 15.51 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
C4O4BrRe+ | 10.50 | CO | EI | Junk, Svec, et al., 1968 | RDSH |
Re+ | >23. | ? | EI | Junk, Svec, et al., 1968 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J.,
Electron impact studies of manganese and rhenium pentacarbonyl halides,
J. Am. Chem. Soc., 1968, 90, 5758. [all data]
Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F.,
Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]
Hall, 1975
Hall, M.B.,
The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls,
J. Am. Chem. Soc., 1975, 97, 2057. [all data]
Ceasar, Milazzo, et al., 1974
Ceasar, G.P.; Milazzo, P.; Cihonski, J.L.; Levenson, R.A.,
Photoelectron spectra of osmium and ruthenium tetroxide,
J. Am. Chem. Soc., 1974, 13, 3035. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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