Nickel, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-

• Formula: C₁₆H₁₄N₂NiO₂
• Molecular weight: 324.9880
• IUPAC Standard InChI: InChI=1S/C16H16N2O2.Ni/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2 Copy

  
• IUPAC Standard InChIKey: DKBSGGSJQXGHBV-UHFFFAOYSA-L Copy
• CAS Registry Number: 14167-20-5
• Chemical structure:
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• Other names: Nickel, [[α,α'-(ethylenedinitrilo)di-o-cresolato](2-)]-; Bis(salicylaldehyde)ethylenediiminatonickel; N,N'-Ethylenebis(salicylideniminato)nickel; Nickel, [N,N'-ethylenebis(salicylaldiminato)]-; Nickel,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

Ionization energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Alikhanyan, Malkerova, et al., 1999
Alikhanyan, A.S.; Malkerova, I.P.; Kuz'mina, N.P.; Gleizes, A.; Julve-Olsina, M.; Sanz, J.L.; Eremenko, I.L., Thermodynamic characteristics of a heteronuclear complex based on [N,N-ethylenebis(salicylaldiminato)]nickel(II), Ni(Salen), and yttrium tris-hexafluoroacetylacetonate Y(HFA)3, Zh. Neorg. Khim., 1999, 44, 6, 969. [all data]

Chen, Pan, et al., 1991
Chen, H.L.; Pan, Y.H.; Groh, S.; Hagan, T.E.; Ridge, D.P., Gas-Phase Charge-Transfer Reactions and Electron Affinities of Macrocyclic, Anionic Nickel Complexes - Ni(SALEN), Ni(Tetraphenylporphyrin), and Derivatives., J. Am. Chem. Soc., 1991, 113, 7, 2766, https://doi.org/10.1021/ja00007a068 . [all data]

Gilbert, Taylor, et al., 1973
Gilbert, W.C.; Taylor, L.T.; Dillard, J.G., Mass spectrometric study of polydentate Schiff base coordination compounds. I. Cobalt(II), nickel(II), and copper(II) complexes of salen and oaben, J. Am. Chem. Soc., 1973, 95, 2477. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  EA	Electron affinity
  ΔsubH	Enthalpy of sublimation

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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