Nickel, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
- Formula: C16H14N2NiO2
- Molecular weight: 324.9880
- IUPAC Standard InChIKey: DKBSGGSJQXGHBV-UHFFFAOYSA-L
- CAS Registry Number: 14167-20-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Nickel, [[α,α'-(ethylenedinitrilo)di-o-cresolato](2-)]-; Bis(salicylaldehyde)ethylenediiminatonickel; N,N'-Ethylenebis(salicylideniminato)nickel; Nickel, [N,N'-ethylenebis(salicylaldiminato)]-; Nickel,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.06 ± 0.10 | IMRE | Chen, Pan, et al., 1991 | SALEN:bis(salicylaldehyde[O-])dioxime of diaminoethane. (0.05eV > PhNO2); B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.57 ± 0.09 | EI | Gilbert, Taylor, et al., 1973 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chen, Pan, et al., 1991
Chen, H.L.; Pan, Y.H.; Groh, S.; Hagan, T.E.; Ridge, D.P.,
Gas-Phase Charge-Transfer Reactions and Electron Affinities of Macrocyclic, Anionic Nickel Complexes - Ni(SALEN), Ni(Tetraphenylporphyrin), and Derivatives.,
J. Am. Chem. Soc., 1991, 113, 7, 2766, https://doi.org/10.1021/ja00007a068
. [all data]
Gilbert, Taylor, et al., 1973
Gilbert, W.C.; Taylor, L.T.; Dillard, J.G.,
Mass spectrometric study of polydentate Schiff base coordination compounds. I. Cobalt(II), nickel(II), and copper(II) complexes of salen and oaben,
J. Am. Chem. Soc., 1973, 95, 2477. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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