Copper(II), benzoylacetonate


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub38.07 ± 0.41kcal/molTERibeiro da Silva, 1995Based on data from 429. to 450. K.
Δsub38.07 ± 0.45kcal/molMERibeiro da Silva, 1995Based on data from 429. to 450. K.
Δsub38.2 ± 1.kcal/molCDa Silva and Reis, 1979 

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
36.38 ± 0.41439.TERibeiro da Silva, 1995Based on data from 429. to 450. K.
36.38 ± 0.45439.MERibeiro da Silva, 1995Based on data from 429. to 450. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
8.37 ± 0.05EIReichert and Westmore, 1970

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C10H9O2Cu+10.7 ± 0.1?EIReichert and Westmore, 1970 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 162974

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014 . [all data]

Da Silva and Reis, 1979
Da Silva, Manuel A.V. Ribeiro; Reis, Ana Maria M.V., Thermochemistry of Copper(II) .BETA.-diketonates. II. Bis(benzoylacetonato)copper(II)., Bull. Chem. Soc. Jpn., 1979, 52, 10, 3080-3083, https://doi.org/10.1246/bcsj.52.3080 . [all data]

Reichert and Westmore, 1970
Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. VI. Mass spectra and appearance potentials of U-diketonates of copper(II), Can. J. Chem., 1970, 48, 3213. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References