pentacarbonylchloromanganese


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-219.5 ± 3.1kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-241.3 ± 2.2kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub14.0 ± 2.0kcal/molN/APilcher and Skinner, 1983See also Connor, Skinner, et al., 1972.; AC
Δsub22. ± 2.kcal/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.12 ± 0.08EIJunk, Svec, et al., 1968RDSH
8.87 ± 0.05PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.94PELichtenberger, Sarapu, et al., 1973Vertical value; LLK
8.83PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
COClMn+11.34COEIJunk, Svec, et al., 1968RDSH
MnCO+~12.1?EIJunk, Svec, et al., 1968RDSH
C2O2ClMn+10.63COEIJunk, Svec, et al., 1968RDSH
MnC3O3+~9.7?EIJunk, Svec, et al., 1968RDSH
MnC5O5+11.4ClEISvec and Junk, 1968RDSH
MnCl+13.85COEIJunk, Svec, et al., 1968RDSH
Mn+~14.8?EIJunk, Svec, et al., 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Connor, Skinner, et al., 1972
Connor, J.A.; Skinner, H.A.; Virmani, Y., Microcalorimetric studies. Thermal decomposition and iodination of metal carbonyls, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 0, 1754, https://doi.org/10.1039/f19726801754 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J., Electron impact studies of manganese and rhenium pentacarbonyl halides, J. Am. Chem. Soc., 1968, 90, 5758. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Lichtenberger, Sarapu, et al., 1973
Lichtenberger, D.L.; Sarapu, A.C.; Fenske, R.F., Photoelectron spectra and electronic structure of pentacarbonylmanganese halides, Inorg. Chem., 1973, 12, 702. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]

Svec and Junk, 1968
Svec, H.J.; Junk, G.A., Thermal reactions in the mass spectrometry of organometallic compounds, Inorg. Chem., 1968, 7, 1688. [all data]


Notes

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