pentacarbonylchloromanganese
- Formula: C5ClMnO5
- Molecular weight: 230.442
- CAS Registry Number: 14100-30-2
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 58.6 ± 8.4 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Connor, Skinner, et al., 1972.; AC |
ΔsubH° | 91. ± 9. | kJ/mol | HAL-HFC | Connor, Zafarani-Moattar, et al., 1982 | MS |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.12 ± 0.08 | EI | Junk, Svec, et al., 1968 | RDSH |
8.87 ± 0.05 | PE | Higginson, Lloyd, et al., 1975 | Vertical value; LLK |
8.94 | PE | Lichtenberger, Sarapu, et al., 1973 | Vertical value; LLK |
8.83 | PE | Evans, Green, et al., 1969 | Vertical value; RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
COClMn+ | 11.3 | 4CO | EI | Junk, Svec, et al., 1968 | RDSH |
MnCO+ | ~12.1 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
C2O2ClMn+ | 10.6 | 3CO | EI | Junk, Svec, et al., 1968 | RDSH |
MnC3O3+ | ~9.7 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
MnC5O5+ | 11.4 | Cl | EI | Svec and Junk, 1968 | RDSH |
MnCl+ | 13.8 | 5CO | EI | Junk, Svec, et al., 1968 | RDSH |
Mn+ | ~14.8 | ? | EI | Junk, Svec, et al., 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Connor, Skinner, et al., 1972
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
Microcalorimetric studies. Thermal decomposition and iodination of metal carbonyls,
J. Chem. Soc., Faraday Trans. 1, 1972, 68, 0, 1754, https://doi.org/10.1039/f19726801754
. [all data]
Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A.,
Organomet., 1982, 1, 1166. [all data]
Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J.,
Electron impact studies of manganese and rhenium pentacarbonyl halides,
J. Am. Chem. Soc., 1968, 90, 5758. [all data]
Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F.,
Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]
Lichtenberger, Sarapu, et al., 1973
Lichtenberger, D.L.; Sarapu, A.C.; Fenske, R.F.,
Photoelectron spectra and electronic structure of pentacarbonylmanganese halides,
Inorg. Chem., 1973, 12, 702. [all data]
Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W.,
Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]
Svec and Junk, 1968
Svec, H.J.; Junk, G.A.,
Thermal reactions in the mass spectrometry of organometallic compounds,
Inorg. Chem., 1968, 7, 1688. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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