Titanium ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) • Carbon monoxide)

By formula: Ti+ + CO = (Ti+ • CO)

Quantity Value Units Method Reference Comment
Δr118. ± 5.9kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 2Carbon monoxide)

By formula: (Ti+ • CO) + CO = (Ti+ • 2CO)

Quantity Value Units Method Reference Comment
Δr113. ± 4.2kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 3Carbon monoxide)

By formula: (Ti+ • 2CO) + CO = (Ti+ • 3CO)

Quantity Value Units Method Reference Comment
Δr100. ± 4.2kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 4Carbon monoxide)

By formula: (Ti+ • 3CO) + CO = (Ti+ • 4CO)

Quantity Value Units Method Reference Comment
Δr87.0 ± 4.2kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 5Carbon monoxide)

By formula: (Ti+ • 4CO) + CO = (Ti+ • 5CO)

Quantity Value Units Method Reference Comment
Δr69.9 ± 4.2kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 6Carbon monoxide)

By formula: (Ti+ • 5CO) + CO = (Ti+ • 6CO)

Quantity Value Units Method Reference Comment
Δr74. ± 3.kJ/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 7Carbon monoxide)

By formula: (Ti+ • 6CO) + CO = (Ti+ • 7CO)

Quantity Value Units Method Reference Comment
Δr51.9 ± 7.1kJ/molCIDTMeyer and Armentrout, 1996RCD

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr154. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Titanium ion (1+) + Acetylene = (Titanium ion (1+) • Acetylene)

By formula: Ti+ + C2H2 = (Ti+ • C2H2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
253. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Ethylene = (Titanium ion (1+) • Ethylene)

By formula: Ti+ + C2H4 = (Ti+ • C2H4)

Quantity Value Units Method Reference Comment
Δr146. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
119. CIDArmentrout and Kickel, 1994gas phase; ΔrH>=, guided ion beam CID; M

Titanium ion (1+) + 1,3-Diazine = (Titanium ion (1+) • 1,3-Diazine)

By formula: Ti+ + C4H4N2 = (Ti+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr214. ± 10.kJ/molCIDTAmunugama and Rodgers, 2001RCD

Titanium ion (1+) + Pyridine = (Titanium ion (1+) • Pyridine)

By formula: Ti+ + C5H5N = (Ti+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr217. ± 9.6kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Titanium ion (1+) + Adenine = (Titanium ion (1+) • Adenine)

By formula: Ti+ + C5H5N5 = (Ti+ • C5H5N5)

Quantity Value Units Method Reference Comment
Δr≤339. ± 15.kJ/molCIDTRodgers and Armentrout, 2002RCD

Titanium ion (1+) + Benzene = (Titanium ion (1+) • Benzene)

By formula: Ti+ + C6H6 = (Ti+ • C6H6)

Quantity Value Units Method Reference Comment
Δr213.kJ/molRAKGapeev and Dunbar, 2002RCD
Δr259. ± 9.2kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
259. (+8.8,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Titanium ion (1+) • Benzene) + Benzene = (Titanium ion (1+) • 2Benzene)

By formula: (Ti+ • C6H6) + C6H6 = (Ti+ • 2C6H6)

Quantity Value Units Method Reference Comment
Δr253. ± 18.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
253. (+18.,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Water = (Titanium ion (1+) • Water)

By formula: Ti+ + H2O = (Ti+ • H2O)

Quantity Value Units Method Reference Comment
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
154. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • Water) + Water = (Titanium ion (1+) • 2Water)

By formula: (Ti+ • H2O) + H2O = (Ti+ • 2H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
136. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 2Water) + Water = (Titanium ion (1+) • 3Water)

By formula: (Ti+ • 2H2O) + H2O = (Ti+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
66.9 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 3Water) + Water = (Titanium ion (1+) • 4Water)

By formula: (Ti+ • 3H2O) + H2O = (Ti+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
83.7 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Ammonia = (Titanium ion (1+) • Ammonia)

By formula: Ti+ + H3N = (Ti+ • H3N)

Quantity Value Units Method Reference Comment
Δr195. ± 7.1kJ/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • Ammonia) + Ammonia = (Titanium ion (1+) • 2Ammonia)

By formula: (Ti+ • H3N) + H3N = (Ti+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr175. ± 15.kJ/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • 2Ammonia) + Ammonia = (Titanium ion (1+) • 3Ammonia)

By formula: (Ti+ • 2H3N) + H3N = (Ti+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr176. ± 15.kJ/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • 3Ammonia) + Ammonia = (Titanium ion (1+) • 4Ammonia)

By formula: (Ti+ • 3H3N) + H3N = (Ti+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr156. ± 10.kJ/molCIDTWalter and Armentrout, 1998RCD

Titanium ion (1+) + titanium = (Titanium ion (1+) • titanium)

By formula: Ti+ + Ti = (Ti+ • Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
244. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • titanium) + titanium = (Titanium ion (1+) • 2titanium)

By formula: (Ti+ • Ti) + Ti = (Ti+ • 2Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
230. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 2titanium) + titanium = (Titanium ion (1+) • 3titanium)

By formula: (Ti+ • 2Ti) + Ti = (Ti+ • 3Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
338. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 3titanium) + titanium = (Titanium ion (1+) • 4titanium)

By formula: (Ti+ • 3Ti) + Ti = (Ti+ • 4Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
340. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 4titanium) + titanium = (Titanium ion (1+) • 5titanium)

By formula: (Ti+ • 4Ti) + Ti = (Ti+ • 5Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
354. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 5titanium) + titanium = (Titanium ion (1+) • 6titanium)

By formula: (Ti+ • 5Ti) + Ti = (Ti+ • 6Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
400. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 6titanium) + titanium = (Titanium ion (1+) • 7titanium)

By formula: (Ti+ • 6Ti) + Ti = (Ti+ • 7Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
278. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 7titanium) + titanium = (Titanium ion (1+) • 8titanium)

By formula: (Ti+ • 7Ti) + Ti = (Ti+ • 8Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
346. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 8titanium) + titanium = (Titanium ion (1+) • 9titanium)

By formula: (Ti+ • 8Ti) + Ti = (Ti+ • 9Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
335. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 9titanium) + titanium = (Titanium ion (1+) • 10titanium)

By formula: (Ti+ • 9Ti) + Ti = (Ti+ • 10Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
344. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 10titanium) + titanium = (Titanium ion (1+) • 11titanium)

By formula: (Ti+ • 10Ti) + Ti = (Ti+ • 11Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
406. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 11titanium) + titanium = (Titanium ion (1+) • 12titanium)

By formula: (Ti+ • 11Ti) + Ti = (Ti+ • 12Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
469.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 12titanium) + titanium = (Titanium ion (1+) • 13titanium)

By formula: (Ti+ • 12Ti) + Ti = (Ti+ • 13Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
321. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 13titanium) + titanium = (Titanium ion (1+) • 14titanium)

By formula: (Ti+ • 13Ti) + Ti = (Ti+ • 14Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
400. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 14titanium) + titanium = (Titanium ion (1+) • 15titanium)

By formula: (Ti+ • 14Ti) + Ti = (Ti+ • 15Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
360. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 15titanium) + titanium = (Titanium ion (1+) • 16titanium)

By formula: (Ti+ • 15Ti) + Ti = (Ti+ • 16Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
344. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 16titanium) + titanium = (Titanium ion (1+) • 17titanium)

By formula: (Ti+ • 16Ti) + Ti = (Ti+ • 17Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
318. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 17titanium) + titanium = (Titanium ion (1+) • 18titanium)

By formula: (Ti+ • 17Ti) + Ti = (Ti+ • 18Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
449.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 18titanium) + titanium = (Titanium ion (1+) • 19titanium)

By formula: (Ti+ • 18Ti) + Ti = (Ti+ • 19Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
409. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 19titanium) + titanium = (Titanium ion (1+) • 20titanium)

By formula: (Ti+ • 19Ti) + Ti = (Ti+ • 20Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
395. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 20titanium) + titanium = (Titanium ion (1+) • 21titanium)

By formula: (Ti+ • 20Ti) + Ti = (Ti+ • 21Ti)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
410. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meyer and Armentrout, 1996
Meyer, F.; Armentrout, P.B., Sequential Bond Energies of Ti(CO)x+, x=1-7, Molec. Phys., 1996, 88, 187. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]


Notes

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