Iron ion (1+)

Gas phase thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar181.86J/mol*KReviewChase, 1998Data last reviewed in June, 1984

Ion clustering data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Iron ion (1+) + Argon = (Iron ion (1+) • Argon)

By formula: Fe+ + Ar = (Fe+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Formaldehyde = (Iron ion (1+) • Formaldehyde)

By formula: Fe+ + CH2O = (Fe+ • CH2O)

Quantity Value Units Method Reference Comment
ΔrH°138. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • Formaldehyde) + Formaldehyde = (Iron ion (1+) • 2Formaldehyde)

By formula: (Fe+ • CH2O) + CH2O = (Fe+ • 2CH2O)

Quantity Value Units Method Reference Comment
ΔrH°164. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 2Formaldehyde) + Formaldehyde = (Iron ion (1+) • 3Formaldehyde)

By formula: (Fe+ • 2CH2O) + CH2O = (Fe+ • 3CH2O)

Quantity Value Units Method Reference Comment
ΔrH°76.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 3Formaldehyde) + Formaldehyde = (Iron ion (1+) • 4Formaldehyde)

By formula: (Fe+ • 3CH2O) + CH2O = (Fe+ • 4CH2O)

Quantity Value Units Method Reference Comment
ΔrH°50.2 ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Methyl radical = (Iron ion (1+) • Methyl radical)

By formula: Fe+ + CH3 = (Fe+ • CH3)

Quantity Value Units Method Reference Comment
ΔrH°240. ± 13.kJ/molCIDTFisher, Schultz, et al., 1989RCD
ΔrH°238. ± 6.7kJ/molCIDTFisher, Schultz, et al., 1989RCD
ΔrH°242. ± 10.kJ/molCIDTSchultz, Elkind, et al., 1988RCD

Iron ion (1+) + CH4Si = (Iron ion (1+) • CH4Si)

By formula: Fe+ + CH4Si = (Fe+ • CH4Si)

Quantity Value Units Method Reference Comment
ΔrH°262. ± 31.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + CH4Si = (Iron ion (1+) • CH4Si)

By formula: Fe+ + CH4Si = (Fe+ • CH4Si)

Quantity Value Units Method Reference Comment
ΔrH°280. ± 46.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Methane = (Iron ion (1+) • Methane)

By formula: Fe+ + CH4 = (Fe+ • CH4)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
57. (+3.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Methane) + Methane = (Iron ion (1+) • 2Methane)

By formula: (Fe+ • CH4) + CH4 = (Fe+ • 2CH4)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
97.1 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Methane) + Methane = (Iron ion (1+) • 3Methane)

By formula: (Fe+ • 2CH4) + CH4 = (Fe+ • 3CH4)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
99.2 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Methane) + Methane = (Iron ion (1+) • 4Methane)

By formula: (Fe+ • 3CH4) + CH4 = (Fe+ • 4CH4)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
74.1 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Carbon monoxide = (Iron ion (1+) • Carbon monoxide)

By formula: Fe+ + CO = (Fe+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°129. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°130. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; determined from MKER and theory; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
131. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 2Carbon monoxide)

By formula: (Fe+ • CO) + CO = (Fe+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°148. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
151. (+14.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 3Carbon monoxide)

By formula: (Fe+ • 2CO) + CO = (Fe+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°69.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
66.1 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 4Carbon monoxide)

By formula: (Fe+ • 3CO) + CO = (Fe+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°97.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
103. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 5Carbon monoxide)

By formula: (Fe+ • 4CO) + CO = (Fe+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°97.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
112. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Carbon monoxide • 2Iron) + Carbon monoxide = (Iron ion (1+) • 4Carbon monoxide • 2Iron)

By formula: (Fe+ • 3CO • 2Fe) + CO = (Fe+ • 4CO • 2Fe)

Quantity Value Units Method Reference Comment
ΔrH°238.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

Iron ion (1+) + Carbon dioxide = (Iron ion (1+) • Carbon dioxide)

By formula: Fe+ + CO2 = (Fe+ • CO2)

Quantity Value Units Method Reference Comment
ΔrH°59.8 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
ΔrH°207. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°231. ± 12.kJ/molCIDTSchroeder, Kretzschmar, et al., 1999RCD

Iron ion (1+) + Carbon disulfide = (Iron ion (1+) • Carbon disulfide)

By formula: Fe+ + CS2 = (Fe+ • CS2)

Quantity Value Units Method Reference Comment
ΔrH°166. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • Carbon disulfide) + Carbon disulfide = (Iron ion (1+) • 2Carbon disulfide)

By formula: (Fe+ • CS2) + CS2 = (Fe+ • 2CS2)

Quantity Value Units Method Reference Comment
ΔrH°188. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Acetylene = (Iron ion (1+) • Acetylene)

By formula: Fe+ + C2H2 = (Fe+ • C2H2)

Quantity Value Units Method Reference Comment
ΔrH°151. ± 7.9kJ/molIRMPDSurya, Ranatunga, et al., 1997RCD

Iron ion (1+) + Ethylene = (Iron ion (1+) • Ethylene)

By formula: Fe+ + C2H4 = (Fe+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°145. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
145. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Ethylene) + Ethylene = (Iron ion (1+) • 2Ethylene)

By formula: (Fe+ • C2H4) + C2H4 = (Fe+ • 2C2H4)

Quantity Value Units Method Reference Comment
ΔrH°151. ± 15.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Iron ion (1+) + C2H6Si = (Iron ion (1+) • C2H6Si)

By formula: Fe+ + C2H6Si = (Fe+ • C2H6Si)

Quantity Value Units Method Reference Comment
ΔrH°287. ± 36.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + C2H6Si = (Iron ion (1+) • C2H6Si)

By formula: Fe+ + C2H6Si = (Fe+ • C2H6Si)

Quantity Value Units Method Reference Comment
ΔrH°260. ± 30.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Ethane = (Iron ion (1+) • Ethane)

By formula: Fe+ + C2H6 = (Fe+ • C2H6)

Quantity Value Units Method Reference Comment
ΔrH°70. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
64.0 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Propene = (Iron ion (1+) • Propene)

By formula: Fe+ + C3H6 = (Fe+ • C3H6)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
145. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + 2-Silaisobutene = (Iron ion (1+) • 2-Silaisobutene)

By formula: Fe+ + C3H8Si = (Fe+ • C3H8Si)

Quantity Value Units Method Reference Comment
ΔrH°270. ± 40.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Propane = (Iron ion (1+) • Propane)

By formula: Fe+ + C3H8 = (Fe+ • C3H8)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
74.9 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + 1,3-Diazine = (Iron ion (1+) • 1,3-Diazine)

By formula: Fe+ + C4H4N2 = (Fe+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°199. ± 7.9kJ/molCIDTAmunugama and Rodgers, 2001RCD

Iron ion (1+) + Pyrrole = (Iron ion (1+) • Pyrrole)

By formula: Fe+ + C4H5N = (Fe+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°226.kJ/molRAKGapeev and Yang, 2000RCD

(Iron ion (1+) • Pyrrole) + Pyrrole = (Iron ion (1+) • 2Pyrrole)

By formula: (Fe+ • C4H5N) + C4H5N = (Fe+ • 2C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°174.kJ/molRAKGapeev and Yang, 2000RCD

Iron ion (1+) + Pyridine = (Iron ion (1+) • Pyridine)

By formula: Fe+ + C5H5N = (Fe+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°223. ± 9.2kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Iron ion (1+) + Adenine = (Iron ion (1+) • Adenine)

By formula: Fe+ + C5H5N5 = (Fe+ • C5H5N5)

Quantity Value Units Method Reference Comment
ΔrH°259. ± 8.8kJ/molCIDTRodgers and Armentrout, 2002RCD

Iron ion (1+) + Benzene = (Iron ion (1+) • Benzene)

By formula: Fe+ + C6H6 = (Fe+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°197.kJ/molRAKGapeev and Dunbar, 2002RCD
ΔrH°207. ± 12.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
208. (+9.6,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Iron ion (1+) • Benzene) + Benzene = (Iron ion (1+) • 2Benzene)

By formula: (Fe+ • C6H6) + C6H6 = (Fe+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°187. ± 16.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
187. (+16.,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Iron ion (1+) + Iron = (Iron ion (1+) • Iron)

By formula: Fe+ + Fe = (Fe+ • Fe)

Quantity Value Units Method Reference Comment
ΔrH°260.kJ/molCIDLoh, Lian, et al., 1988gas phase; M
ΔrH°261.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH>; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
268. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Iron) + Carbon monoxide = (Iron ion (1+) • Carbon monoxide • Iron)

By formula: (Fe+ • Fe) + CO = (Fe+ • CO • Fe)

Quantity Value Units Method Reference Comment
ΔrH°245.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

(Iron ion (1+) • Iron) + Iron = (Iron ion (1+) • 2Iron)

By formula: (Fe+ • Fe) + Fe = (Fe+ • 2Fe)

Quantity Value Units Method Reference Comment
ΔrH°233.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
169. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Iron) + Iron = (Iron ion (1+) • 3Iron)

By formula: (Fe+ • 2Fe) + Fe = (Fe+ • 3Fe)

Quantity Value Units Method Reference Comment
ΔrH°174.kJ/molCIDLoh, Lian, et al., 1988gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
216. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Iron) + Iron = (Iron ion (1+) • 4Iron)

By formula: (Fe+ • 3Fe) + Fe = (Fe+ • 4Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
260. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 4Iron) + Iron = (Iron ion (1+) • 5Iron)

By formula: (Fe+ • 4Fe) + Fe = (Fe+ • 5Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
315. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 5Iron) + Iron = (Iron ion (1+) • 6Iron)

By formula: (Fe+ • 5Fe) + Fe = (Fe+ • 6Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
320. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 6Iron) + Iron = (Iron ion (1+) • 7Iron)

By formula: (Fe+ • 6Fe) + Fe = (Fe+ • 7Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
252. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 7Iron) + Iron = (Iron ion (1+) • 8Iron)

By formula: (Fe+ • 7Fe) + Fe = (Fe+ • 8Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 8Iron) + Iron = (Iron ion (1+) • 9Iron)

By formula: (Fe+ • 8Fe) + Fe = (Fe+ • 9Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
284. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 9Iron) + Iron = (Iron ion (1+) • 10Iron)

By formula: (Fe+ • 9Fe) + Fe = (Fe+ • 10Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
308. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 10Iron) + Iron = (Iron ion (1+) • 11Iron)

By formula: (Fe+ • 10Fe) + Fe = (Fe+ • 11Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
334. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 11Iron) + Iron = (Iron ion (1+) • 12Iron)

By formula: (Fe+ • 11Fe) + Fe = (Fe+ • 12Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 12Iron) + Iron = (Iron ion (1+) • 13Iron)

By formula: (Fe+ • 12Fe) + Fe = (Fe+ • 13Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 13Iron) + Iron = (Iron ion (1+) • 14Iron)

By formula: (Fe+ • 13Fe) + Fe = (Fe+ • 14Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
377. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 14Iron) + Iron = (Iron ion (1+) • 15Iron)

By formula: (Fe+ • 14Fe) + Fe = (Fe+ • 15Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 15Iron) + Iron = (Iron ion (1+) • 16Iron)

By formula: (Fe+ • 15Fe) + Fe = (Fe+ • 16Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
323. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 16Iron) + Iron = (Iron ion (1+) • 17Iron)

By formula: (Fe+ • 16Fe) + Fe = (Fe+ • 17Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
311. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 17Iron) + Iron = (Iron ion (1+) • 18Iron)

By formula: (Fe+ • 17Fe) + Fe = (Fe+ • 18Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
373. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Water = (Iron ion (1+) • Water)

By formula: Fe+ + H2O = (Fe+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°120. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
ΔrH°137.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
128. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Water) + Water = (Iron ion (1+) • 2Water)

By formula: (Fe+ • H2O) + H2O = (Fe+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°171.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
164. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Water) + Water = (Iron ion (1+) • 3Water)

By formula: (Fe+ • 2H2O) + H2O = (Fe+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
76.1 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Water) + Water = (Iron ion (1+) • 4Water)

By formula: (Fe+ • 3H2O) + H2O = (Fe+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Silylene = (Iron ion (1+) • Silylene)

By formula: Fe+ + H2Si = (Fe+ • H2Si)

Quantity Value Units Method Reference Comment
ΔrH°280. ± 50.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Hydrogen = (Iron ion (1+) • Hydrogen)

By formula: Fe+ + H2 = (Fe+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°52.3 ± 0.8kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 45.2 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 45.2 kJ/mol; M

(Iron ion (1+) • Hydrogen) + Hydrogen = (Iron ion (1+) • 2Hydrogen)

By formula: (Fe+ • H2) + H2 = (Fe+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°71.1 ± 0.8kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 65.7 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 65.7 kJ/mol; M

(Iron ion (1+) • 2Hydrogen) + Hydrogen = (Iron ion (1+) • 3Hydrogen)

By formula: (Fe+ • 2H2) + H2 = (Fe+ • 3H2)

Quantity Value Units Method Reference Comment
ΔrH°35. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 31. kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 31. kJ/mol; M

(Iron ion (1+) • 3Hydrogen) + Hydrogen = (Iron ion (1+) • 4Hydrogen)

By formula: (Fe+ • 3H2) + H2 = (Fe+ • 4H2)

Quantity Value Units Method Reference Comment
ΔrH°41. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 36. kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°104.J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 36. kJ/mol; M

(Iron ion (1+) • 4Hydrogen) + Hydrogen = (Iron ion (1+) • 5Hydrogen)

By formula: (Fe+ • 4H2) + H2 = (Fe+ • 5H2)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 9.2 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 9.2 kJ/mol; M

(Iron ion (1+) • 5Hydrogen) + Hydrogen = (Iron ion (1+) • 6Hydrogen)

By formula: (Fe+ • 5H2) + H2 = (Fe+ • 6H2)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 9.6 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°75.7J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; ΔrH(0K) = 9.6 kJ/mol; M

Iron ion (1+) + Ammonia = (Iron ion (1+) • Ammonia)

By formula: Fe+ + H3N = (Fe+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°183. ± 12.kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°161.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Iron ion (1+) • Ammonia) + Ammonia = (Iron ion (1+) • 2Ammonia)

By formula: (Fe+ • H3N) + H3N = (Fe+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°225. ± 12.kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°204.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Iron ion (1+) • 2Ammonia) + Ammonia = (Iron ion (1+) • 3Ammonia)

By formula: (Fe+ • 2H3N) + H3N = (Fe+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°68. ± 13.kJ/molCIDTWalter and Armentrout, 1998RCD

(Iron ion (1+) • 3Ammonia) + Ammonia = (Iron ion (1+) • 4Ammonia)

By formula: (Fe+ • 3H3N) + H3N = (Fe+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°41.8 ± 7.1kJ/molCIDTWalter and Armentrout, 1998RCD

Iron ion (1+) + Krypton = (Iron ion (1+) • Krypton)

By formula: Fe+ + Kr = (Fe+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°30. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Nitrogen = (Iron ion (1+) • Nitrogen)

By formula: Fe+ + N2 = (Fe+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°54.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • Nitrogen) + Nitrogen = (Iron ion (1+) • 2Nitrogen)

By formula: (Fe+ • N2) + N2 = (Fe+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°82.8 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 2Nitrogen) + Nitrogen = (Iron ion (1+) • 3Nitrogen)

By formula: (Fe+ • 2N2) + N2 = (Fe+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°45. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 3Nitrogen) + Nitrogen = (Iron ion (1+) • 4Nitrogen)

By formula: (Fe+ • 3N2) + N2 = (Fe+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°54.0 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 4Nitrogen) + Nitrogen = (Iron ion (1+) • 5Nitrogen)

By formula: (Fe+ • 4N2) + N2 = (Fe+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Xenon = (Iron ion (1+) • Xenon)

By formula: Fe+ + Xe = (Fe+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°41.8 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Fisher, Schultz, et al., 1989
Fisher, E.R.; Schultz, r.H.; Armentrout, P.B., Guided Ion Beam Studies of the State - Specific Reactions of Fe+(6D,4F) with CH3X (X = Cl, Br, I), J. Phys. Chem., 1989, 93, 21, 7382, https://doi.org/10.1021/j100358a027 . [all data]

Schultz, Elkind, et al., 1988
Schultz, R.H.; Elkind, J.L.; Armentrout, P.B., Electronic Effects in C-H and C-C Bond Activation: State-Specific Reactions of Fe+(6D,4F) with Methane, Ethane and Propane, J. Am. Chem. Soc., 1988, 110, 2, 411, https://doi.org/10.1021/ja00210a017 . [all data]

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Tecklenberg, Bricker, et al., 1988
Tecklenberg, R.E.; Bricker, D.L.; Russel, D.H., Laser - Ion Beam Photodissociation Studies of Ionic Cluster Fragments of Iron Carbonyls: Fe(x)(CO)y+ (x = 1 - 3; y = 0 - 6), Organometallics, 1988, 7, 12, 2506, https://doi.org/10.1021/om00102a013 . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Loh, Lian, et al., 1988
Loh, S.K.; Lian, L.; Hales, D.A.; Armentrout, P.B., Collision - Induced Dissociation Processes of Nb4+ and Fe4+: Fission vs Evaporation, J. Chem. Phys., 1988, 89, 1, 610, https://doi.org/10.1063/1.455455 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Bushnell, Kemper, et al., 1995
Bushnell, J.E.; Kemper, P.R.; Bowers, M.T., Factors Affecting sigma Bond Activation in Simple Systems; Measurement of Experimental Binding energies of Fe+(H2)1-6 Clusters, J. Phys. Chem., 1995, 99, 42, 15602, https://doi.org/10.1021/j100042a040 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References

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