Iridium, dicarbonyl(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-, (sp-4-2)-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.85 ± 0.05EIBonati, Distefano, et al., 1971 
9.14PEVan Dam, Terpstra, et al., 1980Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bonati, Distefano, et al., 1971
Bonati, F.; Distefano, G.; Innorta, G.; Minghetti, G.; Pignataro, S., Ionization energies of rhodium and iridium β-diketonates: on the nature of the last occupied orbital, Z. Anorg. Allg. Chem., 1971, 386, 107. [all data]

Van Dam, Terpstra, et al., 1980
Van Dam, H.; Terpstra, A.; Stufkens, D.J.; Oskam, A., UV photoelectron spectroscopic studies of the metal-olefin bond. 2. Bonding in (β-diketonato)rhodium(I) and -iridium(I) carbonyl and olefin complexes, Inorg. Chem., 1980, 19, 3448. [all data]


Notes

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