HypoFluorous acid
- Formula: FHO
- Molecular weight: 36.0057
- IUPAC Standard InChIKey: AQYSYJUIMQTRMV-UHFFFAOYSA-N
- CAS Registry Number: 14034-79-8
- Chemical structure:
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Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
J - Marilyn E. Jacox
Shim - Takehiko Shimanouchi
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 26300 | U | gas | Elliott, 1983 | ||||
Appelman, Downs, et al., 1989 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | OH stretch | 3577.93 | gas | IR | Appelman and Kim, 1972 Burger, Pawelke, et al., 1989 | |
1 | OH stretch | 3572 | m s | Ar | IR | Appelman, Downs, et al., 1989 | |
1 | OH stretch | 3537.1 | s | N2 | IR | Goleb, Claassen, et al., 1972 Appelman, Downs, et al., 1989 | |
1 | OH stretch | 3550 | s | O2 | IR | Appelman, Downs, et al., 1989 | |
2 | Bend | 1353.40 | gas | IR | Appelman and Kim, 1972 Burger, Pawelke, et al., 1988 | ||
2 | Bend | 1350 | vs | Ar | IR | Appelman, Downs, et al., 1989 | |
2 | Bend | 1359.0 | vs | N2 | IR | Goleb, Claassen, et al., 1972 Appelman, Downs, et al., 1989 | |
2 | Bend | 1350 | vs | O2 | IR | Appelman, Downs, et al., 1989 | |
3 | OF stretch | 889.08 | gas | IR | Appelman and Kim, 1972 Burger, Pawelke, et al., 1988 | ||
3 | OF stretch | 888 | m s | Ar | IR | Appelman, Downs, et al., 1989 | |
3 | OF stretch | 886.0 | w m | N2 | IR | Noble and Pimentel, 1968 Goleb, Claassen, et al., 1972 Appelman, Downs, et al., 1989 | |
3 | OF stretch | 884 | m s | O2 | IR | Appelman, Downs, et al., 1989 | |
Additional references: Jacox, 1994, page 51; Kim, Pearson, et al., 1972; Pearson and Kim, 1972; Burger, Pawelke, et al., 1989, 2
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
U | Upper bound |
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Elliott, 1983
Elliott, S.,
Atmos. Environ, 1983, 17, 759. [all data]
Appelman, Downs, et al., 1989
Appelman, E.H.; Downs, A.J.; Gardner, C.J.,
Matrix photochemistry of hypofluorous acid, HOF: oxygen atom transfer and other reactions,
J. Phys. Chem., 1989, 93, 2, 598, https://doi.org/10.1021/j100339a021
. [all data]
Appelman and Kim, 1972
Appelman, E.H.; Kim, H.,
Gas-Phase Infrared Spectra of HOF and DOF,
J. Chem. Phys., 1972, 57, 8, 3272, https://doi.org/10.1063/1.1678752
. [all data]
Burger, Pawelke, et al., 1989
Burger, H.; Pawelke, G.; Rahner, A.; Appelman, E.H.; Halonen, L.,
The high-resolution infrared spectrum of HOF: The interacting ν1 and 2ν2 + ν3 states,
J. Mol. Spectrosc., 1989, 138, 2, 346, https://doi.org/10.1016/0022-2852(89)90003-9
. [all data]
Goleb, Claassen, et al., 1972
Goleb, J.A.; Claassen, H.H.; Studier, M.H.; Appelman, E.H.,
Spectrochim. Acta, 1972, 28A, 65. [all data]
Burger, Pawelke, et al., 1988
Burger, H.; Pawelke, G.; Rahner, A.; Appelman, E.H.; Mills, I.M.,
The infrared spectrum of the ν2 and ν3 bands of H16OF, H18OF, and D16OF,
J. Mol. Spectrosc., 1988, 128, 1, 278, https://doi.org/10.1016/0022-2852(88)90224-X
. [all data]
Noble and Pimentel, 1968
Noble, P.N.; Pimentel, G.C.,
Spectrochim. Acta, 1968, 24A, 7907. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Kim, Pearson, et al., 1972
Kim, H.; Pearson, E.F.; Appelman, E.H.,
Millimeter-Wave Spectrum and Structure of Hypofluorous Acid: HOF and DOF,
J. Chem. Phys., 1972, 56, 1, 1, https://doi.org/10.1063/1.1676830
. [all data]
Pearson and Kim, 1972
Pearson, E.F.; Kim, H.,
Centrifugal Distortion Analysis of Hypofluorous Acid: HOF and DOF,
J. Chem. Phys., 1972, 57, 10, 4230, https://doi.org/10.1063/1.1678053
. [all data]
Burger, Pawelke, et al., 1989, 2
Burger, H.; Pawelke, G.; Sommer, S.; Rahner, A.; Appelman, E.H.; Mills, I.M.,
The high-resolution infrared spectrum of HOF near 2700 cm-1: The ground and 2ν2 states,
J. Mol. Spectrosc., 1989, 136, 1, 197, https://doi.org/10.1016/0022-2852(89)90232-4
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
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