Palladium(II) acetylacetonate


Phase change data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub29.3 ± 2.1kcal/molN/AMalkerova, Alikhanyan, et al., 1991Based on data from 330. to 394. K.
Δsub31.5 ± 4.1kcal/molN/ABurkinshaw and Mortimer, 1984 

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
29.04 ± 0.36402. to 452.N/AZharkova, Stabnikov, et al., 2005 
31.09 ± 0.67347. to 416.MEZharkova, Stabnikov, et al., 2000 
30.5 ± 4.1378.MEBurkinshaw and Mortimer, 1984Based on data from 363. to 393. K.

Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.79PEFragala, Costanzo, et al., 1980Vertical value

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G., Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate, Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Zharkova, Stabnikov, et al., 2005
Zharkova, G.I.; Stabnikov, P.A.; Sysoev, S.A.; Igumenov, I.K., Volatility and crystal lattice energy of palladium(II) chelates, J Struct Chem, 2005, 46, 2, 320-327, https://doi.org/10.1007/s10947-006-0047-8 . [all data]

Zharkova, Stabnikov, et al., 2000
Zharkova, G.I.; Stabnikov, P.A.; Grankin, V.M.; Semyannikov, P.P.; Igumenov, I.K., Russ. J. Coord. Chem., 2000, 26, 8, 576. [all data]

Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C., He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands, Inorg. Chim. Acta, 1980, 40, 15. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References