Palladium(II) acetylacetonate
- Formula: C10H14O4Pd
- Molecular weight: 304.64
- IUPAC Standard InChIKey: RRNUJVZFAXSIII-LIQZFWKRSA-L
- CAS Registry Number: 14024-61-4
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Palladium(II) 2,4-pentanedionate; Palladium acetylacetonate; Palladium, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-; Bis(acetylacetonato)palladium; Bis(2,4-pentanedionato)palladium; Palladium bis(acetoacetonate); Palladium bis(acetylacetonate); Palladium bis(2,4-pentanedionate); Palladium diacetylacetonate; Palladium, bis(2,4-pentanedionato)-; palladium (II) di(4-oxopent-2-en-2-oate)
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 29.3 ± 2.1 | kcal/mol | N/A | Malkerova, Alikhanyan, et al., 1991 | Based on data from 330. to 394. K. |
ΔsubH° | 31.5 ± 4.1 | kcal/mol | N/A | Burkinshaw and Mortimer, 1984 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
29.04 ± 0.36 | 402. to 452. | N/A | Zharkova, Stabnikov, et al., 2005 | |
31.09 ± 0.67 | 347. to 416. | ME | Zharkova, Stabnikov, et al., 2000 | |
30.5 ± 4.1 | 378. | ME | Burkinshaw and Mortimer, 1984 | Based on data from 363. to 393. K. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.79 | PE | Fragala, Costanzo, et al., 1980 | Vertical value |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G.,
Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate,
Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]
Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T.,
Enthalpies of sublimation of transition metal complexes,
J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075
. [all data]
Zharkova, Stabnikov, et al., 2005
Zharkova, G.I.; Stabnikov, P.A.; Sysoev, S.A.; Igumenov, I.K.,
Volatility and crystal lattice energy of palladium(II) chelates,
J Struct Chem, 2005, 46, 2, 320-327, https://doi.org/10.1007/s10947-006-0047-8
. [all data]
Zharkova, Stabnikov, et al., 2000
Zharkova, G.I.; Stabnikov, P.A.; Grankin, V.M.; Semyannikov, P.P.; Igumenov, I.K.,
Russ. J. Coord. Chem., 2000, 26, 8, 576. [all data]
Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C.,
He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands,
Inorg. Chim. Acta, 1980, 40, 15. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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