Palladium(II) acetylacetonate


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub122.7 ± 8.6kJ/molN/AMalkerova, Alikhanyan, et al., 1991Based on data from 330. to 394. K.
Δsub132. ± 17.kJ/molN/ABurkinshaw and Mortimer, 1984 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
121.5 ± 1.5402. to 452.N/AZharkova, Stabnikov, et al., 2005 
130.1 ± 2.8347. to 416.MEZharkova, Stabnikov, et al., 2000 
128. ± 17.378.MEBurkinshaw and Mortimer, 1984Based on data from 363. to 393. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.79PEFragala, Costanzo, et al., 1980Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G., Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate, Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Zharkova, Stabnikov, et al., 2005
Zharkova, G.I.; Stabnikov, P.A.; Sysoev, S.A.; Igumenov, I.K., Volatility and crystal lattice energy of palladium(II) chelates, J Struct Chem, 2005, 46, 2, 320-327, https://doi.org/10.1007/s10947-006-0047-8 . [all data]

Zharkova, Stabnikov, et al., 2000
Zharkova, G.I.; Stabnikov, P.A.; Grankin, V.M.; Semyannikov, P.P.; Igumenov, I.K., Russ. J. Coord. Chem., 2000, 26, 8, 576. [all data]

Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C., He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands, Inorg. Chim. Acta, 1980, 40, 15. [all data]


Notes

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