Bis(acetylacetonato)manganese

• Formula: C₁₀H₁₄MnO₄
• Molecular weight: 253.1538
• IUPAC Standard InChI: InChI=1S/2C5H8O2.Mn/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; Copy

  
• IUPAC Standard InChIKey: ZQZQURFYFJBOCE-FDGPNNRMSA-L Copy
• CAS Registry Number: 14024-58-9
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Manganese, bis(2,4-pentanedionato-O,O')-; Manganese, bis(2,4-pentanedionato)-; Bis(2,4-pentanedionato)manganese; Manganese bis(acetylacetonate); Manganese bis(2,4-pentanedionate); Manganese(II) acetylacetonate; Manganese(II) bis(acetylacetonate); Manganese(2+) acetylacetonate; Manganous acetylacetonate; Manganese(II) 2,4-pentanedionate; Bis(acetylacetonato)manganese(II); Manganese acetylacetonate; Acetylacetone manganese(II); Bis(acetylacetone)manganese; Manganese diacetylacetonate; Manganese, bis(2,4-pentanedionato-κO,κO')-; Manganese, bis(2,4-pentanedionato-κO2,κO4)-; NSC 177707; bis(pentane-2,4-dionato-O,O')manganese
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C₁₀H₁₄MnO₄⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B., Chemia Analityczna, 1981, 26, 1017. [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K., UV photoelectron spectra of some transition metal(II)aAcetylacetonates, Polyhedron, 1983, 2, 43. [all data]

Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series, Inorg. Chem., 1969, 8, 1012. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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