Dicarbonylacetylacetonato iridium

• Formula: C₇H₇IrO₄
• Molecular weight: 347.345
• CAS Registry Number: 14023-80-4
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jesse, Ernsting, et al., 1978
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Thermochim. Acta, 1978, 25, 69. [all data]

Morozova, Semyannikov, et al., 2009
Morozova, N.B.; Semyannikov, P.P.; Trubin, S.V.; Stabnikov, P.P.; Bessonov, A.A.; Zherikova, K.V.; Igumenov, I.K., Vapor pressure of some volatile iridium(I) compounds with carbonyl, acetylacetonate and cyclopentadienyl ligands, J Therm Anal Calorim, 2009, 96, 1, 261-266, https://doi.org/10.1007/s10973-008-9551-8 . [all data]

Jesse, Ernsting, et al., 1978, 2
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Vapour pressure measurements on (acac)M(substituted olefin)2 and (acac)M(CO)2 (M = Rh(I), Ir(I)), Thermochimica Acta, 1978, 25, 1, 69-75, https://doi.org/10.1016/0040-6031(78)80041-0 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Van Dam, Terpstra, et al., 1980
Van Dam, H.; Terpstra, A.; Stufkens, D.J.; Oskam, A., UV photoelectron spectroscopic studies of the metal-olefin bond. 2. Bonding in (β-diketonato)rhodium(I) and -iridium(I) carbonyl and olefin complexes, Inorg. Chem., 1980, 19, 3448. [all data]

Bonati, Distefano, et al., 1971
Bonati, F.; Distefano, G.; Innorta, G.; Minghetti, G.; Pignataro, S., Ionization energies of rhodium and iridium β-diketonates: on the nature of the last occupied orbital, Z. Anorg. Allg. Chem., 1971, 386, 107. [all data]

Notes

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• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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