Dicarbonylacetylacetonato iridium


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C9H15IrO2 (cr) + 2Carbon monoxide (g) = C7H7IrO4 (cr) + 2Ethylene (g)

By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)

Quantity Value Units Method Reference Comment
Δr-74.1 ± 4.6kJ/molDSCJesse, Baks, et al., 1978 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.0PEVan Dam, Terpstra, et al., 1980 
8.6 ± 0.1EIBonati, Distefano, et al., 1971 
8.42PEVan Dam, Terpstra, et al., 1980Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jesse, Baks, et al., 1978
Jesse, A.C.; Baks, A.; Stufkens, D.J.; Vrieze, K., Inorg. Chim. Acta, 1978, 29, 177. [all data]

Van Dam, Terpstra, et al., 1980
Van Dam, H.; Terpstra, A.; Stufkens, D.J.; Oskam, A., UV photoelectron spectroscopic studies of the metal-olefin bond. 2. Bonding in (β-diketonato)rhodium(I) and -iridium(I) carbonyl and olefin complexes, Inorg. Chem., 1980, 19, 3448. [all data]

Bonati, Distefano, et al., 1971
Bonati, F.; Distefano, G.; Innorta, G.; Minghetti, G.; Pignataro, S., Ionization energies of rhodium and iridium β-diketonates: on the nature of the last occupied orbital, Z. Anorg. Allg. Chem., 1971, 386, 107. [all data]


Notes

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