Manganese, phenyl pentacarbonyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-140.3 ± 4.3kcal/molReviewMartinho SimõesThe enthalpy of formation is the average of the results for five iodination reaction enthalpies
Δfgas-140.8 ± 1.7kcal/molReviewMartinho SimõesSelected data

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-160.6 ± 4.1kcal/molReviewMartinho SimõesThe enthalpy of formation is the average of the results for five iodination reaction enthalpies
Δfsolid-161.0 ± 1.3kcal/molReviewMartinho SimõesSelected data

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub20.3 ± 1.1kcal/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982MS
Δsub20.3 ± 1.1kcal/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C11H5MnO5 (solution) + Carbon monoxide (solution) = C12H5MnO6 (solution)

By formula: C11H5MnO5 (solution) + CO (solution) = C12H5MnO6 (solution)

Quantity Value Units Method Reference Comment
Δr-10.8kcal/molEqSCalderazzo, 1977solvent: 2,2'-diethoxydiethyl ether

C12H5MnO6 (cr) = C11H5MnO5 (g) + Carbon monoxide (g)

By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Δr35.4 ± 0.7kcal/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.22 ± 0.05EIJunk, Preston, et al., 1970RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Calderazzo, 1977
Calderazzo, F., Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]

Junk, Preston, et al., 1970
Junk, G.A.; Preston, F.J.; Svec, H.J.; Thompson, D.T., Ligand effects on the ionization potentials and bond energies of some L1L2Fe2(CO)6 complexes, J. Chem. Soc. A, 1970, 3171. [all data]


Notes

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