Manganese, phenyl pentacarbonyl
- Formula: C11H5MnO5
- Molecular weight: 272.0924
- CAS Registry Number: 13985-77-8
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -140.3 ± 4.3 | kcal/mol | Review | Martinho Simões | The enthalpy of formation is the average of the results for five iodination reaction enthalpies |
ΔfH°gas | -140.8 ± 1.7 | kcal/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -160.6 ± 4.1 | kcal/mol | Review | Martinho Simões | The enthalpy of formation is the average of the results for five iodination reaction enthalpies |
ΔfH°solid | -161.0 ± 1.3 | kcal/mol | Review | Martinho Simões | Selected data |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 20.3 ± 1.1 | kcal/mol | HAL-HFC | Connor, Zafarani-Moattar, et al., 1982 | MS |
ΔsubH° | 20.3 ± 1.1 | kcal/mol | C | Connor, Zafarani-Moattar, et al., 1982, 2 | AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C11H5MnO5 (solution) + (solution) = C12H5MnO6 (solution)
By formula: C11H5MnO5 (solution) + CO (solution) = C12H5MnO6 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -10.8 | kcal/mol | EqS | Calderazzo, 1977 | solvent: 2,2'-diethoxydiethyl ether |
C12H5MnO6 (cr) = C11H5MnO5 (g) + (g)
By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35.4 ± 0.7 | kcal/mol | TD-HFC | Connor, Zafarani-Moattar, et al., 1982 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.22 ± 0.05 | EI | Junk, Preston, et al., 1970 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A.,
Organomet., 1982, 1, 1166. [all data]
Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A.,
Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions,
Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011
. [all data]
Calderazzo, 1977
Calderazzo, F.,
Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]
Junk, Preston, et al., 1970
Junk, G.A.; Preston, F.J.; Svec, H.J.; Thompson, D.T.,
Ligand effects on the ionization potentials and bond energies of some L1L2Fe2(CO)6 complexes,
J. Chem. Soc. A, 1970, 3171. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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