Zinc monohydride

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to HZn+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
<0.949978PDRackwitz, Feldman, et al., 1977B

Ionization energy determinations

IE (eV) Method Reference Comment
9.4DERLias, Bartmess, et al., 1988LL

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through July, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 64ZnH
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
C 2Σ+ 41090 1824 H 48  [7.23] 1   [4.7E-4]  [1.533] C ← X V 41200 H
↳Khan, 1962
B 2Σ+ 27587.7 1020.7 Z 16.5  [3.288] 2   [1.40E-4]  [2.273] B → X R 27303.9 Z
↳Stenvinkel, 1936
A 2Πr 23276.9 3 1910.2 Z 40.8  7.4332 4 0.2385  [4.482E-4] 5  1.5119 A → X V 23431.8 6 Z
↳Watson, 1930; Stenvinkel, 1936; Fujioka and Tanaka, 1937; Stenvinkel, Svensson, et al., 1939; Mrozowski, 1940; Veseth, 1971
X 2Σ+ 0 1607.6 Z 55.14 7 .398 6.6794 8 0.2500 9  [4.66E-4] 10  1.59490 11  

Notes

1All lines diffuse; predissociation.
2All observed vibrational levels of B 2Σ show perturbations by A 2Π levels with v ≥ l. The rotational constants in Stenvinkel, 1936 are satisfactorily reproduced by Bv = 3.304 - 0.033(v+1/2) + 0.00060(v+1/2)2 - 0.000245(v+1/2)3 except for v=1, 2, and 3 all of which are close to the intersection of the two potential curves.
3A0 = +342.66 Veseth, 1971, A1 = +342.06 Veseth, 1971 [as recalculated in Veseth, 1971 from the data of Stenvinkel, 1936].
4Rotational constants for v=0 and 1 as recalculated in Veseth, 1971 from the data of Stenvinkel, 1936. Λ-type doubling Δνfe(2Π1/2, v=0) ~ 0.269(J+1/2) - ..., and in 2Π3/2 [see Fujioka and Tanaka, 1937 and Stenvinkel, 1936].
5D1 = 4.46E-4; H0 = +1.34E-8, H1 = +0.9E-8.
6J'=1/2 (average of F1 and {F2}) relative to N"=0. A different definition was used in Stenvinkel, 1936.
7ωeze = -0.4339. Very rapid convergence. The constants (from Stenvinkel, 1936) lead to a discrepancy of nearly 6 cm-1 for the highest observed level, v=5.
8Spin doubling, Δ v12(v=0) = +0.254(N+1/2) - ... [ Stenvinkel, 1936, see also Veseth, 1970], decreasing rapidly with increasing v.
9αv= -0.03765(v+1/2)2 + 0.00897(v+1/2)3 - 0.001479(v+1/2)4.
10D1(E-4 cm-1)= 5.00, D2(E-4 cm-1)= 5.49, D3(E-4 cm-1)= 6.58, D4(E-4 cm-1)= 8.40, D5(E-4 cm-1)= 10.5. Also higher order terms, see Stenvinkel, 1936.
11ESR sp. 13
12Short extrapolation for the ground state.
13In Ar matrix at 4 K Knight and Weltner, 1971.
14From the value for ZnH.
15A0 = +342.82 Veseth, 1971, as recalculated in Veseth, 1971 from the data of Fujioka and Tanaka, 1937.
16Rotational constants recalculated in Veseth, 1971 from data in Fujioka and Tanaka, 1937. Λ-type doubling Δνfe(2Π1/2) ~ +0.170~(J+1/2) - ,.., see Fujioka and Tanaka, 1937.
17H0 = +1.6E-8.
18Spin doubling Δν12 = +0.131(N+1/2), see Fujioka and Tanaka, 1937.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rackwitz, Feldman, et al., 1977
Rackwitz, R.; Feldman, D.; Kaiser, H.J.; Heincke, E., Photodetachment bei einigen zweiatomigen negativen hydridionen: BeH-, MgH-, CaH-, ZnH-, PH-, AsH-, Z. Naturforsch. A:, 1977, 32, 594. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]

Khan, 1962
Khan, M.A., New band systems of ZnH and ZnD in the far ultra-violet region, Proc. Phys. Soc. London, 1962, 80, 599. [all data]

Stenvinkel, 1936
Stenvinkel, G., Dissertation - Ref. to earlier work are reviewed in this paper, Stockholm, 1936, 1. [all data]

Watson, 1930
Watson, W.W., The Zeeman effect in the ZnH and CdH bands, Phys. Rev., 1930, 36, 1134. [all data]

Fujioka and Tanaka, 1937
Fujioka, Y.; Tanaka, Y., Molecular spectra of zinc hydride and deuteride, Sci. Pap. Inst. Phys. Chem. Res. Jpn., 1937, 32, 143-156. [all data]

Stenvinkel, Svensson, et al., 1939
Stenvinkel, G.; Svensson, E.; Olsson, E., Precision wave-lengths for some metal hydride bands and the evidence of their existence in the solar spectrum, Ark. Mat. Astron. Fys., 1939, 26, 1. [all data]

Mrozowski, 1940
Mrozowski, S., Nuclear isotope shift in the spectrum of ZnH, Phys. Rev., 1940, 58, 597. [all data]

Veseth, 1971
Veseth, L., Corrections to the spin-orbit splitting in 2Π states of diatomic molecules, J. Mol. Spectrosc., 1971, 38, 228. [all data]

Veseth, 1970
Veseth, L., Modifications of the doublet energy formulae of a diatomic molecule necessitated by the rotational stretching, J. Phys. B:, 1970, 3, 1677. [all data]

Knight and Weltner, 1971
Knight, L.B., Jr.; Weltner, W., Jr., Hyperfine interaction, chemical bonding, and isotope effect in ZnH, CdH, and HgH molecules, J. Chem. Phys., 1971, 55, 2061. [all data]

Notes

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