Selenium monohydride
- Formula: HSe
- Molecular weight: 79.97
- IUPAC Standard InChIKey: VUGWMQXJZSOYNI-UHFFFAOYSA-N
- CAS Registry Number: 13940-22-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to HSe+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°(+) ion | 262. | kcal/mol | N/A | N/A |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
2.212525 ± 0.000044 | LPD | Stoneman and Larson, 1986 | Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol; B |
2.210 ± 0.030 | PD | Smyth and Brauman, 1972 | B |
2.29921 | N/A | Check, Faust, et al., 2001 | MnO-(t); ; ΔS(EA)=5.5; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.845 ± 0.003 | PI | Gibson, Greene, et al., 1986 | LBLHLM |
9.79 | S | Donovan, Little, et al., 1972 | LLK |
De-protonation reactions
Se- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 339.9 ± 1.1 | kcal/mol | D-EA | Vandevraye, Drag, et al., 2012 | gas phase; Given: 2.0206046(11) eV; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 333.9 ± 1.2 | kcal/mol | H-TS | Vandevraye, Drag, et al., 2012 | gas phase; Given: 2.0206046(11) eV; B |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stoneman and Larson, 1986
Stoneman, R.C.; Larson, D.J.,
Photodetachment spectroscopy of SeH- in a magnetic field,
J. Phys. B:, 1986, 19, 405. [all data]
Wagman, Evans, et al., 1982
Wagman, D.D.; Evans, W.H.; Parker, V.B.; Schumm, R.H.; Halow, I.; Bailey, S.M.; Churney, K.L.; Nuttall, R.L.,
The NBS Tables of Chemical Thermodynamic Properties (NBS Tech Note 270),
J. Phys. Chem. Ref. Data, Supl. 1, 1982, 11. [all data]
Smyth and Brauman, 1972
Smyth, K.C.; Brauman, J.I.,
Photodetachment of an electron from selenide ion the electron affinity and spin- orbit coupling constant for SeH,
J. Chem. Phys., 1972, 56, 5993. [all data]
Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S.,
Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements,
J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l
. [all data]
Gibson, Greene, et al., 1986
Gibson, S.T.; Greene, J.P.; Berkowitz, J.,
A photoionization study of SeH and H2Se,
J. Chem. Phys., 1986, 85, 4815. [all data]
Donovan, Little, et al., 1972
Donovan, R.J.; Little, D.J.; Konstantatos, J.,
Vacuum ultraviolet spectra of transient molecules and radicals,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1812. [all data]
Vandevraye, Drag, et al., 2012
Vandevraye, M.; Drag, C.; Blondel, C.,
Electron affinity of selenium measured by photodetachment microscopy,
Phys. Rev. A, 2012, 85, 1, 015401, https://doi.org/10.1103/PhysRevA.85.015401
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.