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Chlorine trioxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to ClO3+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
4.25 ± 0.10LPESWang and Wang, 2000Vertical Detachment Energy: 4.65±0.10 eV.; B
>3.19997EIAEAlekseev, Fedorova, et al., 1983From ClO3F; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.4 ± 0.10EIAlekseev, Zyubina, et al., 1989LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang and Wang, 2000
Wang, X.B.; Wang, L.S., The electronic structure and electron affinities of higher chlorine oxide radicals ClOx (x=2-4) from photoelectron spectroscopy of ClOx- anions, J. Chem. Phys., 2000, 113, 24, 10928-10933, https://doi.org/10.1063/1.1326067 . [all data]

Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V., Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]

Alekseev, Zyubina, et al., 1989
Alekseev, V.I.; Zyubina, T.S.; Zyubin, A.S.; Baluev, A.V., Mass-spectrometric and quantum-chemical investigation of thermochemical characteristics of chlorine oxides, J. Am. Chem. Soc., 1989, 2092. [all data]


Notes

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