Bromine monofluoride
- Formula: BrF
- Molecular weight: 98.902
- IUPAC Standard InChI: InChI=1S/BrF/c1-2
- IUPAC Standard InChIKey: MZJUGRUTVANEDW-UHFFFAOYSA-N
- CAS Registry Number: 13863-59-7
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to BrF+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.86 | PE | Dyke, Josland, et al., 1984 | LBLHLM |
| 11.77 ± 0.01 | PE | Colbourn, Dyke, et al., 1978 | LLK |
| 12.09 ± 0.01 | PE | DeKock, Higginson, et al., 1972 | LLK |
| 11.78 ± 0.01 | PE | DeKock, Higginson, et al., 1972 | LLK |
| 11.8 ± 0.2 | EI | Irsa and Friedman, 1958 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dyke, Josland, et al., 1984
Dyke, J.M.; Josland, G.D.; Snijders, J.G.; Boerrigter, P.M.,
Ionization energies of the diatomic halogens and interhalogens studied with relativistic hartree-fock-slater calculations,
Chem. Phys., 1984, 91, 419. [all data]
Colbourn, Dyke, et al., 1978
Colbourn, E.A.; Dyke, J.M.; Fayad, N.K.; Morris, A.,
The He(I) photoelectron spectra of BrF and IF,
J. Electron Spectrosc. Relat. Phenom., 1978, 14, 443. [all data]
DeKock, Higginson, et al., 1972
DeKock, R.L.; Higginson, B.R.; Lloyd, D.R.; Breeze, A.; Cruickshank, D.W.J.; Armstrong, D.R.,
Photoelectron spectra of halides. V. Experimental theoretical study of the electronic structures of ClF, ClF3, BrF and BrF3,
Mol. Phys., 1972, 24, 1059. [all data]
Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L.,
Mass spectra of halogen fluorides,
J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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