tetrakis(trifluorophosphine)nickel

• Formula: F₁₂NiP₄
• Molecular weight: 410.5693
• IUPAC Standard InChI: InChI=1S/4F3P.Ni/c4*1-4(2)3; Copy

  
• IUPAC Standard InChIKey: TXBNRHVYQQTHJK-UHFFFAOYSA-N Copy
• CAS Registry Number: 13859-65-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Nickel, tetrakis(phosphorus trifluoride)-
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 (l) =  (cr) + 4 (g)

By formula: F₁₂NiP₄ (l) = Ni (cr) + 4F₃P (g)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Brown and Connor, 1974
Brown, D.L.S.; Connor, J.A., Skinner, H. A. J. Chem. Soc., Faraday Trans. I, 1974, 70, 1649. [all data]

Bassett, Higginson, et al., 1974
Bassett, P.J.; Higginson, B.R.; Lloyd, D.R.; Lynaugh, N.; Roberts, P.J., Helium-I photoelectron spectra of tetrakis(trifluoro- phosphine)-nickel(O), -palladium(O), and -platinum(O), J. Chem. Soc. Dalton Trans., 1974, 2316. [all data]

Muller, Fenderl, et al., 1971
Muller, J.; Fenderl, K.; Mertschenk, B., Die Donor-Akzeptor-Eigenschaften des Liganden Trifluorphosphin in Ubergangsmetallkomplexen, Chem. Ber., 1971, 104, 700. [all data]

Kiser, Krassoi, et al., 1967
Kiser, R.W.; Krassoi, M.A.; Clark, R.J., Mass spectrometric study of tetrakis(trifluorophosphine)nickel(0), J. Am. Chem. Soc., 1967, 89, 3653. [all data]

Hillier, Saunders, et al., 1970
Hillier, I.H.; Saunders, V.R.; Ware, M.J.; Bassett, P.J.; Lloyd, D.R.; Lynaugh, N., On the bonding and the photoelectron spectra of Ni(PF₃)₄ and Pt(PF₃)₄, Chem. Commun., 1970, 1316. [all data]

Green, King, et al., 1970
Green, J.C.; King, D.I.; Eland, J.H.D., Photoelectron spectra of trifluorophosphine and its complexes Ni(PF₃), and Pt(PF₃)₄, Chem. Commun., 1970, 1121. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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