Plutonium trifluoride
- Formula: F3Pu
- Molecular weight: 301
- CAS Registry Number: 13842-83-6
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to F3Pu+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.6 ± 0.5 | EI | Kleinschmidt, 1988 | LL |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FPu+ | 18.8 ± 0.3 | 2F | EI | Kleinschmidt, 1988 | LL |
| PuF+ | 17.8 ± 0.5 | ? | EI | Kent, 1968 | RDSH |
| F2Pu+ | 12.5 ± 0.2 | F | EI | Kleinschmidt, 1988 | LL |
| PuF2+ | 12.6 ± 0.5 | F | EI | Kent, 1968 | RDSH |
| Pu+ | 25.3 ± 0.2 | 3F | EI | Kleinschmidt, 1988 | LL |
| Pu+ | 25.0 ± 1.0 | ? | EI | Kent, 1968 | RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kleinschmidt, 1988
Kleinschmidt, P.D.,
Thermochemistry of the plutonium fluorides from electron impact studies,
J. Chem. Phys., 1988, 89, 6897. [all data]
Kent, 1968
Kent, R.A.,
Mass spectrometric studies of plutonium compounds at high temperatures. II. The enthalpy of sublimation of plutonium(III) fluoride and the dissociation energy of plutonium(I) fluoride,
J. Am. Chem. Soc., 1968, 90, 5657. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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