Molybdenum pentafluoride

Formula: F₅Mo
Molecular weight: 190.95
CAS Registry Number: 13819-84-6
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Other data available:
- Gas phase thermochemistry data
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Gas phase ion energetics data

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to F₅Mo⁺ (ion structure unspecified)

Ionization energy determinations

IE (eV)	Method	Reference	Comment
10.5 ± 0.3	EI	Malkerova, Alikhanyan, et al., 1980	LLK
10.8 ± 0.2	EI	Alikhanyan, Steblevskii, et al., 1978	LLK
10.60 ± 0.10	EI	Hildenbrand, 1976	LLK

References

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Malkerova, Alikhanyan, et al., 1980
Malkerova, I.P.; Alikhanyan, A.S.; Pervov, V.S.; Butskii, V.D.; Gorgoraki, V.I., Heats of formation of molybdenum sulphide fluorides MoSF₃ and MoSF₄, Russ. J. Inorg. Chem., 1980, 25, 1145, In original 2067. [all data]

Alikhanyan, Steblevskii, et al., 1978
Alikhanyan, A.S.; Steblevskii, A.V.; Malkerova, I.P.; Pervov, V.S.; Butskii, V.D.; Gorgoraki, V.I., Mass spectrometric study of the sublimation of molybdenum trifluoride, Russ. J. Inorg. Chem., 1978, 23, 814. [all data]

Hildenbrand, 1976
Hildenbrand, D.L., Thermochemical studies of the gaseous lower valent fluorides of molybdenum, J. Chem. Phys., 1976, 65, 614. [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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