Digermane


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
184.5 to 304.73.953751129.447-19.239Stull, 1947Coefficents calculated by NIST from author's data.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
12.5 ± 0.3EISaalfeld and Svec, 1963RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Ge+13.3 ± 0.3?EISaalfeld and Svec, 1963RDSH
GeH3+10.26 ± 0.10?EISaalfeld and Svec, 1966RDSH
Ge2+13.1 ± 0.33H2EISaalfeld and Svec, 1963RDSH
Ge2H+13.0 ± 0.32H2+HEISaalfeld and Svec, 1963RDSH
Ge2H2+12.9 ± 0.32H2EISaalfeld and Svec, 1963RDSH
Ge2H3+12.8 ± 0.3H2+HEISaalfeld and Svec, 1963RDSH
Ge2H4+12.7 ± 0.3H2EISaalfeld and Svec, 1963RDSH
Ge2H5+12.6 ± 0.3HEISaalfeld and Svec, 1963RDSH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3d     Symmetry Number σ = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1g 1 GeH3 s-str 2068  C  ia 2068 S p liq.
a1g 2 GeH3 s-deform 832  C  ia 832 VW p liq.
a1g 3 GeGe str 268  C  ia 268.4 S p liq.
a1u 4 Torsion 146  E  ia  ia
a2u 5 GeH3 s-str 2077  B 2077.0 VS gas  ia
a2u 6 GeH3 s-deform 756  B 756.0 VS gas  ia
eu 7 GeH3 d-str 2091  B 2090.7 S gas  ia
eu 8 GeH3 d-deform 879  B 879.0 S gas  ia
eu 9 GeH3 rock 370  B 370.3 M gas  ia
eg 10 GeH3 d-str 2081  E CF
eg 11 GeH3 d-deform 880  C 879.6 M dp liq.
eg 12 GeH3 rock 567  C 566.6 W dp liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
VWVery weak
iaInactive
pPolarized
dpDepolarized
CFCalculated frequency
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
E15~30 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Saalfeld and Svec, 1963
Saalfeld, F.E.; Svec, H.J., The mass spectra of volatile hydrides. II. Some higher hydrides of the group IVB and VB elements, Inorg. Chem., 1963, 2, 50. [all data]

Saalfeld and Svec, 1966
Saalfeld, F.E.; Svec, H.J., Mass spectra of volatile hydrides. IV. Silylgermane, J. Phys. Chem., 1966, 70, 1753. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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