Silylgermane
- Formula: GeH6Si
- Molecular weight: 106.77
- IUPAC Standard InChI: InChI=1S/GeH6Si/c1-2/h1-2H3
- IUPAC Standard InChIKey: VJFOQKOUHKDIGD-UHFFFAOYSA-N
- CAS Registry Number: 13768-63-3
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 5.98 | 220. | Spanier and MacDiarmid, 1963 | Based on data from 190. to 250. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 10.20 ± 0.03 | EI | Saalfeld and Svec, 1966 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| GeH3+ | 11.32 ± 0.14 | ? | EI | Saalfeld and Svec, 1966 | |
| SiH3+ | 12.01 ± 0.09 | ? | EI | Saalfeld and Svec, 1966 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spanier and MacDiarmid, 1963
Spanier, Edward J.; MacDiarmid, Alan G.,
The Synthesis of Germylsilane from Silane and Germane in a Silent Electric Discharge,
Inorg. Chem., 1963, 2, 1, 215-216, https://doi.org/10.1021/ic50005a055
. [all data]
Saalfeld and Svec, 1966
Saalfeld, F.E.; Svec, H.J.,
Mass spectra of volatile hydrides. IV. Silylgermane,
J. Phys. Chem., 1966, 70, 1753. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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